Synthesis, Characterization, and Application of Ternary CuO/ZrO@S-doped G-CN Hybrid Nanocomposites

Overview

Journal RSC Adv

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2025 Feb 28

PMID 40017639

Authors

Nigussie Alebachew

Taye B Demissie

H C Ananda Murthy

Bedasa Abdisa Gonfa

Karel G von Eschwege

Elizabeth Coetsee

Ernst H G Langner

Jayadev

B H Doreswamy

Affiliations

Soon will be listed here.

Abstract

Graphitic carbon nitride (g-CN) is utilized across various fields, including catalysis, hydrogen production, and biosensing, due to its basic surface sites. However, g-CN often shows limited efficiency in such applications, mainly due to challenges related to absorption and low conductivity. This study aimed to synthesize S-doped g-CN/CuO/ZrO-based semiconducting ternary nanocomposites (NCs) for catalytic applications using a chemical precipitation method. A straightforward gas-templating technique was applied to achieve one-step nano-structuring of S-doped g-CN at 550 °C. The interactions between cubical CuO structures, monoclinic ZrO, and flower-like S-doped g-CN morphologies were investigated using a range of analytical techniques, including X-ray diffraction (XRD), high-resolution X-ray photoelectron spectroscopy (HR-XPS), high-resolution scanning electron microscopy (HR-SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy (DRS), thermogravimetric analysis (TGA), differential thermal analysis (DTA), Brunauer-Emmett-Teller (BET) surface area analysis, and photoluminescence (PL) studies. The superior performance of CuO/ZrO@S-doped g-CN (30%) nanocomposite is attributed to its smaller crystalline size, optimized band gap energy, and large surface area. These features collectively enhance electron-hole pair separation efficiency and increase the number of active sites for adsorption and reaction. Such improvements not only enhance sensitivity but also boost sensor efficiency through better charge carrier generation, selective detection capabilities, and facilitated charge transfer. These enhancements also contribute to reducing recombination losses and accelerating signal generation and g-CN transport. These synthesized ternary NCs were applied to bisphenol A (BPA) detection. The electrocatalytic behaviour of the modified carbon paste electrode (CPE) was assessed by measuring BPA cyclic voltammetry (CV) under ideal conditions (pH 5). The CuO/ZrO@S-doped g-CN (30%)/CPE system demonstrated high electrocatalytic performance, achieving reproducibility with a 1.7 μM detection limit and 2.1 μM limit of quantification. Overall, this research highlights the potential of synthetic ternary NCs as versatile materials for environmental remediation applications.

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