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Photolithography-Induced Doping and Interface Modulation for High-Performance Monolayer WSe P-Type Transistors

Overview
Journal Nano Lett
Specialty Biotechnology
Date 2025 Feb 21
PMID 39984307
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Abstract

To mitigate Fermi-level pinning (FLP) at the contact of two-dimensional (2D) transition metal dichalcogenides and enhance their hole carrier concentration, a 1.8 nm-thick p-doping layer is formed via photolithography. This surface treatment significantly reduces the contact resistance () to ∼4.8 kΩ·um in monolayer (1L) WSe p-type field-effect transistors (p-FETs) and increases hole carrier concentration by 1.4 times, resulting in a field-effect mobility of ∼75 cm/V·s. After subsequent helium ion-beam lithography, the Fermi level can still be modulated from 4.25 to 4.55 eV due to the ultrathin buffer layer. This approach enables high-performance p-FETs with 1L-WSe channels, achieving a maximum on-state current density of 420 μA/μm at a of -1 V and ultralow of ∼0.8 kΩ·um by the combination of the MoO encapsulation for additional p-doping. These results demonstrate that 1L-WSe p-FETs can attain performance comparable to 2D n-FETs, paving the way for high-performance complementary metal-oxide semiconductor transistors with 2D channels.

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