Non-monotonic Information and Shape Evolution of Polymers Enabled by Spatially Programmed Crystallization and Melting

Overview

Journal Chem Bio Eng

Date 2025 Feb 20

PMID 39974185

Authors

Xing Zhang

Yichen Zhou

Mengzhe Han

Ying Zheng

Junfeng Liu

Yongzhong Bao

Guorong Shan

Chengtao Yu

Pengju Pan

Affiliations

Soon will be listed here.

Abstract

Stimuli-responsive polymer materials are a kind of intelligent material which can sense and respond to external stimuli. However, most current stimuli-responsive polymers only exhibit a monotonic response to a single constant stimulus but cannot achieve dynamic evolution. Herein, we report a method to achieve a non-monotonic response under a single stimulus by regionalizing the crystallization and melting kinetics in semicrystalline polymers. Based on the influence of cross-linking on the crystallization and melting kinetics of polymers, we employ light to spatially regulate the cross-linking degree in polymers. The prepared material can realize the self-evolved encryption of pattern information and the non-monotonic shape evolution without complex multiple stimuli. By combination of pattern and shape evolution, the coupled encryption of shape and pattern can be achieved. This approach empowers polymers with the ability to evolve under constant stimulus, offering insights into the functional design of polymer materials.

References

Deng S, Huang L, Wu J, Pan P, Zhao Q, Xie T . Bioinspired Dual-Mode Temporal Communication via Digitally Programmable Phase-Change Materials. Adv Mater. 2021; 33(24):e2008119. DOI: 10.1002/adma.202008119. View

Yang L, Zhang G, Zheng N, Zhao Q, Xie T . A Metallosupramolecular Shape-Memory Polymer with Gradient Thermal Plasticity. Angew Chem Int Ed Engl. 2017; 56(41):12599-12602. DOI: 10.1002/anie.201706949. View

Woo T, Liang X, Evans D, Fernandez O, Kretschmer F, Reiter S . The dynamics of pattern matching in camouflaging cuttlefish. Nature. 2023; 619(7968):122-128. PMC: 10322717. DOI: 10.1038/s41586-023-06259-2. View

Liang H, Wu Y, Zhang Y, Chen E, Wei Y, Ji Y . Elastomers Grow into Actuators. Adv Mater. 2023; 35(12):e2209853. DOI: 10.1002/adma.202209853. View

Zhang Y, Liu K, Liu T, Ni C, Chen D, Guo J . Differential diffusion driven far-from-equilibrium shape-shifting of hydrogels. Nat Commun. 2021; 12(1):6155. PMC: 8546058. DOI: 10.1038/s41467-021-26464-9. View

Huang L, Jiang R, Wu J, Song J, Bai H, Li B . Ultrafast Digital Printing toward 4D Shape Changing Materials. Adv Mater. 2016; 29(7). DOI: 10.1002/adma.201605390. View

Feng Y, Ma Z, Zhong S, Wang C, Chen X . Stepwise Stimuli-Responsive, Multicolor-Chromic Perylene Bisimide/Polyvinyl Alcohol Co-assembly System for Information Encryption. Chemistry. 2023; 29(43):e202301074. DOI: 10.1002/chem.202301074. View

Wang S, Kaneko D, Okajima M, Yasaki K, Tateyama S, Kaneko T . Hyperbranched polycoumarates with photofunctional multiple shape memory. Angew Chem Int Ed Engl. 2013; 52(42):11143-8. DOI: 10.1002/anie.201305647. View

Gagliano M, Renton M, Depczynski M, Mancuso S . Experience teaches plants to learn faster and forget slower in environments where it matters. Oecologia. 2014; 175(1):63-72. DOI: 10.1007/s00442-013-2873-7. View

10.

Zhao W, Yue C, Liu L, Liu Y, Leng J . Research Progress of Shape Memory Polymer and 4D Printing in Biomedical Application. Adv Healthc Mater. 2022; 12(16):e2201975. DOI: 10.1002/adhm.202201975. View

11.

Zhuo S, Song C, Rong Q, Zhao T, Liu M . Shape and stiffness memory ionogels with programmable pressure-resistance response. Nat Commun. 2022; 13(1):1743. PMC: 8976034. DOI: 10.1038/s41467-022-29424-z. View

12.

Li G, Wang S, Liu Z, Liu Z, Xia H, Zhang C . 2D-to-3D Shape Transformation of Room-Temperature-Programmable Shape-Memory Polymers through Selective Suppression of Strain Relaxation. ACS Appl Mater Interfaces. 2018; 10(46):40189-40197. DOI: 10.1021/acsami.8b16094. View

13.

Taboada C, Delia J, Chen M, Ma C, Peng X, Zhu X . Glassfrogs conceal blood in their liver to maintain transparency. Science. 2022; 378(6626):1315-1320. PMC: 9984244. DOI: 10.1126/science.abl6620. View

14.

Lendlein A, Langer R . Biodegradable, elastic shape-memory polymers for potential biomedical applications. Science. 2002; 296(5573):1673-6. DOI: 10.1126/science.1066102. View

15.

Ding M, Yuan W, Xu S, Yu C, Zheng Y, Zhou J . Light-Induced Crystalline Size Heterogeneity of Polymers Enables Programmable Writing, Morphing, and Mechanical Performance Designing. ACS Macro Lett. 2022; 11(6):739-746. DOI: 10.1021/acsmacrolett.2c00237. View

16.

Zhu C, Bai T, Wang H, Ling J, Huang F, Hong W . Dual-Encryption in a Shape-Memory Hydrogel with Tunable Fluorescence and Reconfigurable Architecture. Adv Mater. 2021; 33(29):e2102023. DOI: 10.1002/adma.202102023. View

17.

Rahman A, Sartore L, Bignotti F, Di Landro L . Autonomic self-healing in epoxidized natural rubber. ACS Appl Mater Interfaces. 2013; 5(4):1494-502. DOI: 10.1021/am303015e. View