» Articles » PMID: 39795235

Recent Advances in the Tunable Optoelectromagnetic Properties of PEDOTs

Overview
Journal Molecules
Publisher MDPI
Date 2025 Jan 11
PMID 39795235
Authors
Affiliations
Soon will be listed here.
Abstract

Conducting polymers represent a crucial class of functional materials with widespread applications in diverse fields. Among these, poly(3,4-ethylenedioxythiophene) (PEDOT) and its derivatives have garnered significant attention due to their distinctive optical, electronic, and magnetic properties, as well as their exceptional tunability. These properties often exhibit intricate interdependencies, manifesting as synergistic, concomitant, or antagonistic relationships. In optics, PEDOTs are renowned for their high transparency and unique photoelectric responses. From an electrical perspective, they display exceptional conductivity, thermoelectric, and piezoelectric performance, along with notable electrochemical activity and stability, enabling a wide array of electronic applications. In terms of magnetic properties, PEDOTs demonstrate outstanding electromagnetic shielding efficiency and microwave absorption capabilities. Moreover, these properties can be precisely tailored through molecular structure modifications, chemical doping, and composite formation to suit various application requirements. This review systematically examines the mechanisms underlying the optoelectromagnetic properties of PEDOTs, highlights their tunability, and outlines prospective research directions. By providing critical theoretical insights and technical references, this review aims to advance the application landscape of PEDOTs.

References
1.
Vaagensmith B, Reza K, Hasan M, Elbohy H, Adhikari N, Dubey A . Environmentally Friendly Plasma-Treated PEDOT:PSS as Electrodes for ITO-Free Perovskite Solar Cells. ACS Appl Mater Interfaces. 2017; 9(41):35861-35870. DOI: 10.1021/acsami.7b10987. View

2.
Jiang Q, Zhang J, Mao Z, Yao Y, Zhao D, Jia Y . Room-Temperature Ferromagnetism in Perylene Diimide Organic Semiconductor. Adv Mater. 2022; 34(14):e2108103. DOI: 10.1002/adma.202108103. View

3.
Rivnay J, Inal S, Collins B, Sessolo M, Stavrinidou E, Strakosas X . Structural control of mixed ionic and electronic transport in conducting polymers. Nat Commun. 2016; 7:11287. PMC: 4838877. DOI: 10.1038/ncomms11287. View

4.
Lo C, Wu Y, Awuyah E, Meli D, Nguyen D, Wu R . Influence of the molecular weight and size distribution of PSS on mixed ionic-electronic transport in PEDOT:PSS. Polym Chem. 2022; 13(19):2764-2775. PMC: 9523623. DOI: 10.1039/d2py00271j. View

5.
Li B, Cai C, Liu Y, Wang F, Yang B, Li Q . Ultrasensitive mechanical/thermal response of a P(VDF-TrFE) sensor with a tailored network interconnection interface. Nat Commun. 2023; 14(1):4000. PMC: 10326000. DOI: 10.1038/s41467-023-39476-4. View