Syntheses, Structures, and Photocatalytic and Sonocatalytic Degradations of Methyl Blue of Cu(II) and Mn(II) Coordination Polymers Based on Tri(triazole) and Dicarboxylate Ligands

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2024 Nov 27

PMID 39598678

Authors

Chao Yin

Xing Wang

Jian-Gang Ding

Bao-Long Li

Bing Wu

Chuan-Jiang Hu

Affiliations

Soon will be listed here.

Abstract

Cu(II) and Mn(II) coordination polymers [Cu(ttpa)(sub)] ( or ) and {[Mn(ttpa)(nip)(HO)]·3HO} ( or ) (ttpa = tris(4-(1,2,4-triazol-1-yl)phenyl)amine, Hsub = suberic acid, nip = 5-nitroisophthalicate) were hydrothermally prepared and the structures were characterized. exhibited a 2D (4,4) network based on [Cu(COO)] dimers with upper and lower dangled ttpa ligands and a 2D → 3D polythreaded network. showed a 2D (4,4) network with dangled uncoordinated triazole rings from ttpa ligands and nitro groups from nip ligands and a 2D → 3D polythreaded network. data of and were 1.88 eV and 2.11 eV. and exhibited good catalytic activity for the decomposition of methyl blue (MB) under visible light and supersound irradiation. The decomposition mechanism using was explored. The holes (h) and OH hydroxyl radicals played the main roles, and the O superoxide radicals played certain auxiliary roles in the decomposition of MB within the catalyst.

References

Lin Z, Lu J, Hong M, Cao R . Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications. Chem Soc Rev. 2014; 43(16):5867-95. DOI: 10.1039/c3cs60483g. View

Butorlin O, Petrova A, Toikka Y, Kolesnikov I, Orlov S, Ryazantsev M . The Structure and Optical Properties of Luminescent Europium Terephthalate Antenna Metal-Organic Frameworks Doped by Yttrium, Gadolinium, and Lanthanum Ions. Molecules. 2024; 29(15). PMC: 11314237. DOI: 10.3390/molecules29153558. View

Dong J, Shi Z, Li B, Wang L . Synthesis of a novel 2D zinc(ii) metal-organic framework for photocatalytic degradation of organic dyes in water. Dalton Trans. 2019; 48(47):17626-17632. DOI: 10.1039/c9dt03727f. View

Mosleh S, Rahimi M, Ghaedi M, Dashtian K . Sonophotocatalytic degradation of trypan blue and vesuvine dyes in the presence of blue light active photocatalyst of Ag3PO4/Bi2S3-HKUST-1-MOF: Central composite optimization and synergistic effect study. Ultrason Sonochem. 2016; 32:387-397. DOI: 10.1016/j.ultsonch.2016.04.007. View

Martin-Garcia Y, Tapiador J, Orcajo G, Ayala J, Lago A . [BMIM][X] Ionic Liquids Supported on a Pillared-Layered Metal-Organic Framework: Synthesis, Characterization, and Adsorption Properties. Molecules. 2024; 29(15). PMC: 11314118. DOI: 10.3390/molecules29153644. View

Alvaro M, Carbonell E, Ferrer B, Llabres I Xamena F, Garcia H . Semiconductor behavior of a metal-organic framework (MOF). Chemistry. 2007; 13(18):5106-12. DOI: 10.1002/chem.200601003. View

Qian L, Blatov V, Wang Z, Ding J, Zhu L, Li K . Sonochemical synthesis and characterization of four nanostructural nickel coordination polymers and photocatalytic degradation of methylene blue. Ultrason Sonochem. 2019; 56:213-228. DOI: 10.1016/j.ultsonch.2019.04.015. View

Siadatnasab F, Farhadi S, Khataee A . Sonocatalytic performance of magnetically separable CuS/CoFeO nanohybrid for efficient degradation of organic dyes. Ultrason Sonochem. 2018; 44:359-367. DOI: 10.1016/j.ultsonch.2018.02.051. View

Liu X, Lu L, Zhu M, Englert U . Design and synthesis of three new copper coordination polymers: efficient degradation of an organic dye at alkaline pH. Dalton Trans. 2021; 50(39):13866-13876. DOI: 10.1039/d1dt02463a. View

10.

Dutta B, Ahmed F, Hedayetullah Mir M . Coordination polymers: a promising candidate for photo-responsive electronic device application. Dalton Trans. 2023; 52(46):17084-17098. DOI: 10.1039/d3dt02768f. View

11.

Zeng B, Zhang Y, Chen Y, Liu G, Li Y, Chen L . 3-D Antimonotungstate Framework Based on 2,6-Hpdca-connecting Iron-Cerium Heterometallic Krebs-type Polyoxotungstates for Detecting Small Biomolecules. Inorg Chem. 2021; 60(4):2663-2671. DOI: 10.1021/acs.inorgchem.0c03556. View

12.

Elenkova D, Dimitrova Y, Tsvetkov M, Morgenstern B, Milanova M, Todorovsky D . Investigation of the Sensing Properties of Lanthanoid Metal-Organic Frameworks (Ln-MOFs) with Terephthalic Acid. Molecules. 2024; 29(15). PMC: 11314416. DOI: 10.3390/molecules29153713. View