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Evolution of the Surface Phase Transitions in IrTe

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Journal Sci Rep
Specialty Science
Date 2024 Oct 22
PMID 39438668
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Abstract

The phase transitions in IrTe have been extensively studied but the symmetry at each phase is yet to be settled. Employing second harmonic generation (SHG) measurements over a temperature range of 4 -300 K, we probe the evolution of the symmetry of IrTe. Our results indicate shifts in two distinct transition temperatures (T and T with T > T) through thermal cycling, providing an explanation for the variations of reported values in literature. The SHG polarimetry measurements identify symmetries in different temperature ranges, confirming the trigonal symmetry above T, the triclinic symmetry between T and T, and the coexistence of multiple stripe phases below T. The most striking feature is the reemergence of a trigonal phase as reflected by six-fold symmetry below ~ 10 K which is likely responsible for phenomena observed at low temperatures.

References
1.
Chowdhury T, Sadler E, Kempa T . Progress and Prospects in Transition-Metal Dichalcogenide Research Beyond 2D. Chem Rev. 2020; 120(22):12563-12591. DOI: 10.1021/acs.chemrev.0c00505. View

2.
Li Q, Lin W, Yan J, Chen X, Gianfrancesco A, Singh D . Bond competition and phase evolution on the IrTe₂ surface. Nat Commun. 2014; 5:5358. DOI: 10.1038/ncomms6358. View

3.
Ko K, Lee H, Kim D, Yang J, Cheong S, Eom M . Charge-ordering cascade with spin-orbit Mott dimer states in metallic iridium ditelluride. Nat Commun. 2015; 6:7342. DOI: 10.1038/ncomms8342. View

4.
Saleh G, Artyukhin S . First-Principles Theory of Phase Transitions in IrTe. J Phys Chem Lett. 2020; 11(6):2127-2132. PMC: 7997575. DOI: 10.1021/acs.jpclett.0c00012. View

5.
Eom M, Kim K, Jo Y, Yang J, Choi E, Min B . Dimerization-induced Fermi-surface reconstruction in IrTe2. Phys Rev Lett. 2015; 113(26):266406. DOI: 10.1103/PhysRevLett.113.266406. View