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White Fluorescent Organic Light-Emitting Diodes with 100% Power Conversion

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Specialty Biology
Date 2024 Sep 18
PMID 39290967
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Abstract

Energy-efficient lighting sources are desired to provide another solution of carbon emission reduction. White organic light-emitting diodes are promising, because of theoretical internal quantum efficiencies for 100% electric-to-light conversion. However, pure organic fluorescent materials still face a challenge in harvesting triplet excitons for radiation. Herein, we report a white fluorescent organic light-emitting diode having an external quantum efficiency of 30.7% and a power efficiency of 120.2 lm W. In the single emissive layers, we use blue thermally activated delayed fluorescent emitters to sensitize a yellow fluorescent emitter. Transient photoluminescence and electroluminescence analyses suggest that a blue thermally activated delayed fluorescent molecule with ~100% reverse intersystem crossing efficiency and negligible triplet nonradiative rate constant completely converts triplet to singlet, suppressing triplet quenching by a yellow fluorescent emitter and ensuring 100% power conversion.

Citing Articles

Flexible Crystal Heterojunctions of Low-Dimensional Organic Metal Halides Enabling Color-Tunable Space-Resolved Optical Waveguides.

Lin Y, Liu S, Yan D Research (Wash D C). 2023; 6:0259.

PMID: 37915767 PMC: 10616971. DOI: 10.34133/research.0259.

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