» Articles » PMID: 39269078

Enhancing Perovskite Solar Cell Performance Through Propylamine Hydroiodide Passivation

Overview
Date 2024 Sep 13
PMID 39269078
Authors
Affiliations
Soon will be listed here.
Abstract

In recent years, the power conversion efficiency of perovskite solar cells has increased rapidly. Perovskites can be prepared using simple and cost-effective solution methods. However, the perovskite films obtained are usually polycrystalline and contain numerous defects. Passivation of these defects is crucial for enhancing the performance of solar cells. Here, we report the use of propylamine hydroiodide (PAI) for defect passivation. We found that PAI can result in higher-efficiency cells by reducing the defects and suppressing non-radiative recombination. Consequently, n-i-p perovskite solar cells with a certificated efficiency of 21% were obtained. In addition, PAI exhibited excellent performance in p-i-n devices by serving as a buried interface layer, leading to an improved efficiency of 23%.

References
1.
Manser J, Saidaminov M, Christians J, Bakr O, Kamat P . Making and Breaking of Lead Halide Perovskites. Acc Chem Res. 2016; 49(2):330-8. DOI: 10.1021/acs.accounts.5b00455. View

2.
Liang P, Liao C, Chueh C, Zuo F, Williams S, Xin X . Additive enhanced crystallization of solution-processed perovskite for highly efficient planar-heterojunction solar cells. Adv Mater. 2014; 26(22):3748-54. DOI: 10.1002/adma.201400231. View

3.
Fang X, Ding J, Yuan N, Sun P, Lv M, Ding G . Graphene quantum dot incorporated perovskite films: passivating grain boundaries and facilitating electron extraction. Phys Chem Chem Phys. 2017; 19(8):6057-6063. DOI: 10.1039/c6cp06953c. View

4.
Alharbi E, Alyamani A, Kubicki D, Uhl A, Walder B, Alanazi A . Atomic-level passivation mechanism of ammonium salts enabling highly efficient perovskite solar cells. Nat Commun. 2019; 10(1):3008. PMC: 6614363. DOI: 10.1038/s41467-019-10985-5. View

5.
Chen H, Liu C, Xu J, Maxwell A, Zhou W, Yang Y . Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands. Science. 2024; 384(6692):189-193. DOI: 10.1126/science.adm9474. View