Promoting Electrocatalytic Oxygen Reactions Using Advanced Heterostructures for Rechargeable Zinc-Air Battery Applications

Overview

Journal ACS Nano

Publisher American Chemical Society

Specialty Biotechnology

Date 2024 Aug 12

PMID 39129497

Authors

Dingrong Qiu

Huihui Wang

Tingting Ma

Jiangdu Huang

Zhen Meng

Dayong Fan

Chris R Bowen

Huidan Lu

Yongping Liu

Sundaram Chandrasekaran

Affiliations

Soon will be listed here.

Abstract

In order to facilitate electrochemical oxygen reactions in electrically rechargeable zinc-air batteries (ZABs), there is a need to develop innovative approaches for efficient oxygen electrocatalysts. Due to their reliability, high energy density, material abundance, and ecofriendliness, rechargeable ZABs hold promise as next-generation energy storage and conversion devices. However, the large-scale application of ZABs is currently hindered by the slow kinetics of the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). However, the development of heterostructure-based electrocatalysts has the potential to surpass the limitations imposed by the intrinsic properties of a single material. This Account begins with an explanation of the configurations of ZABs and the fundamentals of the oxygen electrochemistry of the air electrode. Then, we summarize recent progress with respect to the variety of heterostructures that exploit bifunctional electrocatalytic reactions and overview their impact on ZAB performance. The range of heterointerfacial engineering strategies for improving the ORR/OER and ZAB performance includes tailoring the surface chemistry, dimensionality of catalysts, interfacial charge transfer, mass and charge transport, and morphology. We highlight the multicomponent design approaches that take these features into account to create advanced highly active bifunctional catalysts. Finally, we discuss the challenges and future perspectives on this important topic that aim to enhance the bifunctional activity and performance of zinc-air batteries.

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References

Lv X, Wang Z, Lai Z, Liu Y, Ma T, Geng J . Rechargeable Zinc-Air Batteries: Advances, Challenges, and Prospects. Small. 2023; 20(4):e2306396. DOI: 10.1002/smll.202306396. View

Tian H, Li Z, Feng G, Yang Z, Fox D, Wang M . Stable, high-performance, dendrite-free, seawater-based aqueous batteries. Nat Commun. 2021; 12(1):237. PMC: 7801520. DOI: 10.1038/s41467-020-20334-6. View

Deng D, Novoselov K, Fu Q, Zheng N, Tian Z, Bao X . Catalysis with two-dimensional materials and their heterostructures. Nat Nanotechnol. 2016; 11(3):218-30. DOI: 10.1038/nnano.2015.340. View

Gao L, Chang S, Zhang Z . High-Quality CoFeP Nanocrystal/N, P Dual-Doped Carbon Composite as a Novel Bifunctional Electrocatalyst for Rechargeable Zn-Air Battery. ACS Appl Mater Interfaces. 2021; 13(19):22282-22291. DOI: 10.1021/acsami.1c00484. View

Yan Y, Shu C, Zeng T, Wen X, Liu S, Deng D . Surface-Preferred Crystal Plane Growth Enabled by Underpotential Deposited Monolayer toward Dendrite-Free Zinc Anode. ACS Nano. 2022; 16(6):9150-9162. DOI: 10.1021/acsnano.2c01380. View

Zong H, Liu W, Li M, Gong S, Yu K, Zhu Z . Oxygen-Terminated NbCO MXene with Interfacial Self-Assembled COF as a Bifunctional Catalyst for Durable Zinc-Air Batteries. ACS Appl Mater Interfaces. 2022; 14(8):10738-10746. DOI: 10.1021/acsami.1c25264. View

Jiang Y, Deng Y, Liang R, Fu J, Gao R, Luo D . d-Orbital steered active sites through ligand editing on heterometal imidazole frameworks for rechargeable zinc-air battery. Nat Commun. 2020; 11(1):5858. PMC: 7673988. DOI: 10.1038/s41467-020-19709-6. View

Tian Y, An Y, Wei C, Xi B, Xiong S, Feng J . Flexible and Free-Standing TiCT MXene@Zn Paper for Dendrite-Free Aqueous Zinc Metal Batteries and Nonaqueous Lithium Metal Batteries. ACS Nano. 2019; 13(10):11676-11685. DOI: 10.1021/acsnano.9b05599. View

Xiao Y, Cheng Z, Zhao Y, Qu L . Highly crumpled nanocarbons as efficient metal-free electrocatalysts for zinc-air batteries. Nanoscale. 2018; 10(33):15706-15713. DOI: 10.1039/c8nr04068k. View

10.

Li R, Fan W, Rao P, Luo J, Li J, Deng P . Multimetallic Single-Atom Catalysts for Bifunctional Oxygen Electrocatalysis. ACS Nano. 2023; 17(18):18128-18138. DOI: 10.1021/acsnano.3c04945. View

11.

Wang N, Chen D, Ning S, Lao J, Xu J, Luo M . Fe Cluster Modified Co S Heterojunction: Highly Efficient Photoelectrocatalyst for Overall Water Splitting and Flexible Zinc-Air Batteries. Adv Mater. 2023; 36(2):e2306138. DOI: 10.1002/adma.202306138. View

12.

Lei H, Tan S, Ma L, Liu Y, Liang Y, Javed M . Strongly Coupled NiCoO Nanocrystal/MXene Hybrid through In Situ Ni/Co-F Bonds for Efficient Wearable Zn-Air Batteries. ACS Appl Mater Interfaces. 2020; 12(40):44639-44647. DOI: 10.1021/acsami.0c11185. View

13.

Zhu Z, Jiang T, Ali M, Meng Y, Jin Y, Cui Y . Rechargeable Batteries for Grid Scale Energy Storage. Chem Rev. 2022; 122(22):16610-16751. DOI: 10.1021/acs.chemrev.2c00289. View

14.

Liu J, Liu H, Chen H, Du X, Zhang B, Hong Z . Progress and Challenges Toward the Rational Design of Oxygen Electrocatalysts Based on a Descriptor Approach. Adv Sci (Weinh). 2020; 7(1):1901614. PMC: 6947511. DOI: 10.1002/advs.201901614. View

15.

Qin Q, Jang H, Chen L, Li P, Wei T, Liu X . Coupling a Low Loading of IrP, PtP, or PdP with Heteroatom-Doped Nanocarbon for Overall Water-Splitting Cells and Zinc-Air Batteries. ACS Appl Mater Interfaces. 2019; 11(18):16461-16473. DOI: 10.1021/acsami.8b21155. View

16.

Wang F, Borodin O, Gao T, Fan X, Sun W, Han F . Highly reversible zinc metal anode for aqueous batteries. Nat Mater. 2018; 17(6):543-549. DOI: 10.1038/s41563-018-0063-z. View

17.

Fan X, Zhang R, Sui S, Liu X, Liu J, Shi C . Starch-Based Superabsorbent Hydrogel with High Electrolyte Retention Capability and Synergistic Interface Engineering for Long-Lifespan Flexible Zinc-Air Batteries. Angew Chem Int Ed Engl. 2023; 62(22):e202302640. DOI: 10.1002/anie.202302640. View

18.

Tang K, Hu H, Xiong Y, Chen L, Zhang J, Yuan C . Hydrophobization Engineering of the Air-Cathode Catalyst for Improved Oxygen Diffusion towards Efficient Zinc-Air Batteries. Angew Chem Int Ed Engl. 2022; 61(24):e202202671. DOI: 10.1002/anie.202202671. View

19.

Hu H, Wang X, Paul Attfield J, Yang M . Metal nitrides for seawater electrolysis. Chem Soc Rev. 2023; 53(1):163-203. DOI: 10.1039/d3cs00717k. View

20.

Chandrasekaran S, Yao L, Deng L, Bowen C, Zhang Y, Chen S . Recent advances in metal sulfides: from controlled fabrication to electrocatalytic, photocatalytic and photoelectrochemical water splitting and beyond. Chem Soc Rev. 2019; 48(15):4178-4280. DOI: 10.1039/c8cs00664d. View