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Pentafluorophenyl Copper-Biarylsulfoxide Complexes: Synthesis and Photoreactivity

Overview
Journal Molecules
Publisher MDPI
Specialty Biology
Date 2024 Jul 27
PMID 39064910
Authors
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Abstract

Pentafluorophenyl copper(I)-biarylsulfoxide complexes, existing as [Cu(CF)]L, both in solution and in the solid state, were prepared and thoroughly characterized. Subsequently, the photochemistry of the complexes was explored, showing inherent photoreactivity of the biarylsulfoxide moiety within the coordination sphere of the copper. Photoinduced cross-coupling reactions between the anthryl moiety of bis-anthracenylsulfoxide and pentafluorobenzene, and synthesis of CuO (cuprite), were demonstrated.

Citing Articles

New Sulfenate Sources for Double Pallado-Catalyzed Cross-Coupling Reaction: Application in Symmetrical Biarylsulfoxide Synthesis, and Evidence of TADF Properties.

Magne V, Cretoiu I, Mallet-Ladeira S, Maerten E, Madec D Molecules. 2024; 29(20).

PMID: 39459178 PMC: 11509984. DOI: 10.3390/molecules29204809.

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