Pentafluorophenyl Copper-Biarylsulfoxide Complexes: Synthesis and Photoreactivity
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Abstract
Pentafluorophenyl copper(I)-biarylsulfoxide complexes, existing as [Cu(CF)]L, both in solution and in the solid state, were prepared and thoroughly characterized. Subsequently, the photochemistry of the complexes was explored, showing inherent photoreactivity of the biarylsulfoxide moiety within the coordination sphere of the copper. Photoinduced cross-coupling reactions between the anthryl moiety of bis-anthracenylsulfoxide and pentafluorobenzene, and synthesis of CuO (cuprite), were demonstrated.
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References
1.
Sipos G, Drinkel E, Dorta R
. The emergence of sulfoxides as efficient ligands in transition metal catalysis. Chem Soc Rev. 2015; 44(11):3834-60.
DOI: 10.1039/c4cs00524d.
View
2.
Brayton C
. Dimethyl sulfoxide (DMSO): a review. Cornell Vet. 1986; 76(1):61-90.
View
3.
David N
. The pharmacology of dimethyl sulfoxide. Annu Rev Pharmacol. 1972; 12:353-74.
DOI: 10.1146/annurev.pa.12.040172.002033.
View
4.
Sheldrick G
. SHELXT - integrated space-group and crystal-structure determination. Acta Crystallogr A Found Adv. 2014; 71(Pt 1):3-8.
PMC: 4283466.
DOI: 10.1107/S2053273314026370.
View
5.
Sheldrick G
. Crystal structure refinement with SHELXL. Acta Crystallogr C Struct Chem. 2015; 71(Pt 1):3-8.
PMC: 4294323.
DOI: 10.1107/S2053229614024218.
View