Host-Guest Metal-Organic Frameworks-Based Long-Afterglow Luminescence Materials

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2024 Jul 13

PMID 38998941

Authors

Zhi-Chen Zhang

Zhi-Gang Gu

Jian Zhang

Affiliations

Soon will be listed here.

Abstract

Long-afterglow materials have a broad of applications in optoelectronic devices, sensors, medicine and other fields due to their excellent luminescent properties. The host-guest long-afterglow MOFs material combines the advantages of multi-component characteristics and the stability of MOFs, which improves its luminous performance and expands its other properties. This review introduces the classification, synthesis and application of host-guest MOFs materials with long afterglow. Due to their rigid frames and multi-channel characteristics, MOFs can load common guest materials including rare earth metals, organic dyes, carbon dots, etc. The synthesis methods of loading guest materials into MOFs include solvothermal synthesis, post-encapsulation, post-modification, etc. Those long-afterglow host-guest MOFs have a wide range of applications in the fields of sensors, information security and biological imaging.

Citing Articles

An exploration of the ocular mysteries linking nanoparticles to the patho-therapeutic effects against keratitis.

Qu S, Zheng S, Muhammad S, Huang L, Guo B J Nanobiotechnology. 2025; 23(1):184.

PMID: 40050881 PMC: 11887204. DOI: 10.1186/s12951-025-03230-3.

Research Progress Towards and Prospects of Carbon Dots Derived from Tea and Chinese Medicinal Materials.

Tang X, Gong Z, Lang Y, Chen H, Huang S, Lv Y Nanomaterials (Basel). 2025; 15(3).

PMID: 39940152 PMC: 11820907. DOI: 10.3390/nano15030171.

References

Chen M, Li S, Wen L, Xu Z, Li H, Ding L . Exploration of double Z-type ternary composite long-afterglow/graphitic carbon nitride@metal-organic framework for photocatalytic degradation of methylene blue. J Colloid Interface Sci. 2022; 629(Pt A):409-421. DOI: 10.1016/j.jcis.2022.08.189. View

Ma Y, Fang X, Xiao G, Yan D . Dynamic Manipulating Space-Resolved Persistent Luminescence in Core-Shell MOFs Heterostructures via Reversible Photochromism. Angew Chem Int Ed Engl. 2021; 61(2):e202114100. DOI: 10.1002/anie.202114100. View

Lo Presti F, Pellegrino A, Consoli N, Malandrino G . Green Ultrasound-Assisted Synthesis of Rare-Earth-Based MOFs. Molecules. 2023; 28(16). PMC: 10458194. DOI: 10.3390/molecules28166088. View

Liu D, Huxford R, Lin W . Phosphorescent nanoscale coordination polymers as contrast agents for optical imaging. Angew Chem Int Ed Engl. 2011; 50(16):3696-700. PMC: 3432504. DOI: 10.1002/anie.201008277. View

Wang H, Wang L, Xiao F . Metal@Zeolite Hybrid Materials for Catalysis. ACS Cent Sci. 2020; 6(10):1685-1697. PMC: 7596864. DOI: 10.1021/acscentsci.0c01130. View

Huang M, Liang Z, Huang J, Wen Y, Zhu Q, Wu X . Introduction of Multicomponent Dyes into 2D MOFs: A Strategy to Fabricate White Light-Emitting MOF Composite Nanosheets. ACS Appl Mater Interfaces. 2023; 15(8):11131-11140. DOI: 10.1021/acsami.2c22568. View

Ran Z, Liu J, Zhuang J, Liu Y, Hu C . Multicolor Afterglow from Carbon Dots: Preparation and Mechanism. Small Methods. 2023; 8(1):e2301013. DOI: 10.1002/smtd.202301013. View

Nadar S, Rathod V . One pot synthesis of α-amylase metal organic framework (MOF)-sponge via dip-coating technique. Int J Biol Macromol. 2019; 138:1035-1043. DOI: 10.1016/j.ijbiomac.2019.07.099. View

Terraschke H, Wickleder C . UV, Blue, Green, Yellow, Red, and Small: Newest Developments on Eu(2+)-Doped Nanophosphors. Chem Rev. 2015; 115(20):11352-78. DOI: 10.1021/acs.chemrev.5b00223. View

10.

Knedel T, Buss S, Maisuls I, Daniliuc C, Schlusener C, Brandt P . Encapsulation of Phosphorescent Pt(II) Complexes in Zn-Based Metal-Organic Frameworks toward Oxygen-Sensing Porous Materials. Inorg Chem. 2020; 59(10):7252-7264. DOI: 10.1021/acs.inorgchem.0c00678. View

11.

Zhang H, Wang B, Yu X, Li J, Shang J, Yu J . Carbon Dots in Porous Materials: Host-Guest Synergy for Enhanced Performance. Angew Chem Int Ed Engl. 2020; 59(44):19390-19402. DOI: 10.1002/anie.202006545. View

12.

Luo Z, Liu Y, Liu Y, Li C, Li Y, Li Q . Integrated Afterglow and Self-Trapped Exciton Emissions in Hybrid Metal Halides for Anti-Counterfeiting Applications. Adv Mater. 2022; 34(18):e2200607. DOI: 10.1002/adma.202200607. View

13.

Hou Y, Zhang Z, Lu S, Yuan J, Zhu Q, Chen W . Highly Emissive Perylene Diimide-Based Metallacages and Their Host-Guest Chemistry for Information Encryption. J Am Chem Soc. 2020; 142(44):18763-18768. DOI: 10.1021/jacs.0c09904. View

14.

Zhou B, Qi Z, Yan D . Highly Efficient and Direct Ultralong All-Phosphorescence from Metal-Organic Framework Photonic Glasses. Angew Chem Int Ed Engl. 2022; 61(39):e202208735. DOI: 10.1002/anie.202208735. View

15.

Wu H, Lu X, Chen J, Yang X, Qin W, Ma L . Long Afterglow of a Nonporous Coordination Polymer with Tunable Room-Temperature Phosphorescence by the Doping of Dye Molecules. Inorg Chem. 2021; 60(2):846-851. DOI: 10.1021/acs.inorgchem.0c02888. View

16.

Wei H, Zhang Q, Deng Z, Guan G, Dong Z, Cao H . Lanthanide Inorganic Nanoparticles Enhance Semiconducting Polymer Nanoparticles Afterglow Luminescence for In Vivo Afterglow/Magnetic Resonance Imaging. Anal Chem. 2024; 96(19):7697-7705. DOI: 10.1021/acs.analchem.4c00747. View

17.

Chen X, Li M, Ge L, Liu S, Lv W, Yu Y . Ultralong Red Room-Temperature Phosphorescence of 2D Organic-Inorganic Metal Halide Perovskites for Afterglow Red LEDs and X-ray Scintillation Applications. Inorg Chem. 2023; 62(40):16538-16546. DOI: 10.1021/acs.inorgchem.3c02380. View

18.

Li C, Song Z, Li Y, Lou K, Qiu J, Yang Z . Enhanced NIR downconversion luminescence by precipitating nano Ca5(PO4)3F crystals in Eu2+-Yb3+ co-doped glass. Spectrochim Acta A Mol Biomol Spectrosc. 2013; 114:575-8. DOI: 10.1016/j.saa.2013.05.074. View

19.

Guo W, Xia W, Cai K, Wu Y, Qiu B, Liang Z . Kinetic-Controlled Formation of Bimetallic Metal-Organic Framework Hybrid Structures. Small. 2017; 13(41). DOI: 10.1002/smll.201702049. View

20.

Kuila S, George S . Phosphorescence Energy Transfer: Ambient Afterglow Fluorescence from Water-Processable and Purely Organic Dyes via Delayed Sensitization. Angew Chem Int Ed Engl. 2020; 59(24):9393-9397. DOI: 10.1002/anie.202002555. View