Co-Doped Porous Carbon/Carbon Nanotube Heterostructures Derived from ZIF-L@ZIF-67 for Efficient Microwave Absorption

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2024 Jun 19

PMID 38893301

Authors

Liming He

Hongda Xu

Yang Cui

Jian Qi

Xiaolong Wang

Quan Jin

Affiliations

Soon will be listed here.

Abstract

Carbon-based magnetic metal composites derived from metal-organic frameworks (MOFs) are promising materials for the preparation of broadband microwave absorbers. In this work, the leaf-like co-doped porous carbon/carbon nanotube heterostructure was obtained using ZIF-L@ZIF-67 as precursor. The number of carbon nanotubes can be controlled by varying the amount of ZIF-67, thus regulating the dielectric constant of the sample. An optimum reflection loss of -42.2 dB is attained when ZIF-67 is added at 2 mmol. An effective absorption bandwidth (EAB) of 4.8 GHz is achieved with a thickness of 2.2 mm and a filler weight of 12%. The excellent microwave absorption (MA) ability is generated from the mesopore structure, uniform heterogeneous interfaces, and high conduction loss. The work offers useful guidelines to devise and prepare such nanostructured materials for MA materials.

References

Yin P, Zhang L, Wang J, Feng X, Zhao L, Rao H . Preparation of SiO-MnFeO Composites via One-Pot Hydrothermal Synthesis Method and Microwave Absorption Investigation in S-Band. Molecules. 2019; 24(14). PMC: 6680861. DOI: 10.3390/molecules24142605. View

Yin Y, Liu X, Wei X, Yu R, Shui J . Porous CNTs/Co Composite Derived from Zeolitic Imidazolate Framework: A Lightweight, Ultrathin, and Highly Efficient Electromagnetic Wave Absorber. ACS Appl Mater Interfaces. 2016; 8(50):34686-34698. DOI: 10.1021/acsami.6b12178. View

Sun Q, Yang X, Shu T, Yang X, Qiao M, Wang D . In Situ Synthesis of C-N@NiFeO@MXene/Ni Nanocomposites for Efficient Electromagnetic Wave Absorption at an Ultralow Thickness Level. Molecules. 2023; 28(1). PMC: 9822367. DOI: 10.3390/molecules28010233. View

Liu C, Lin L, Sun Q, Wang J, Huang R, Chen W . Site-specific growth of MOF-on-MOF heterostructures with controllable nano-architectures: beyond the combination of MOF analogues. Chem Sci. 2021; 11(14):3680-3686. PMC: 8152623. DOI: 10.1039/d0sc00417k. View

Xu X, Ran F, Fan Z, Lai H, Cheng Z, Lv T . Cactus-Inspired Bimetallic Metal-Organic Framework-Derived 1D-2D Hierarchical Co/N-Decorated Carbon Architecture toward Enhanced Electromagnetic Wave Absorbing Performance. ACS Appl Mater Interfaces. 2019; 11(14):13564-13573. DOI: 10.1021/acsami.9b00356. View

Qu Z, Wang Y, Yang P, Zheng W, Li N, Bai J . Enhanced Electromagnetic Wave Absorption Properties of Ultrathin MnO Nanosheet-Decorated Spherical Flower-Shaped Carbonyl Iron Powder. Molecules. 2022; 27(1). PMC: 8746408. DOI: 10.3390/molecules27010135. View

Huang J, Gu H, Li N, Yang H, Chen G, Zhang L . Polypyrrole/Schiff Base Composite as Electromagnetic Absorbing Material with High and Tunable Absorption Performance. Molecules. 2022; 27(19). PMC: 9573551. DOI: 10.3390/molecules27196160. View

Lu Y, Yang P, Li Y, Wen D, Luo J, Wang S . A Facile Synthesis of NiFe-Layered Double Hydroxide and Mixed Metal Oxide with Excellent Microwave Absorption Properties. Molecules. 2021; 26(16). PMC: 8398574. DOI: 10.3390/molecules26165046. View

Lee S, Oh S, Oh M . Atypical Hybrid Metal-Organic Frameworks (MOFs): A Combinative Process for MOF-on-MOF Growth, Etching, and Structure Transformation. Angew Chem Int Ed Engl. 2019; 59(3):1327-1333. DOI: 10.1002/anie.201912986. View

10.

Gu W, Shi J, Zhang J, Jia Q, Liu C, Ge H . Fabrication and Investigation of the Microwave Absorption of Nonwovens Modified by Carbon Nanotubes and Graphene Flakes. Molecules. 2023; 28(17). PMC: 10490006. DOI: 10.3390/molecules28176419. View

11.

Wang K, Chen Y, Tian R, Li H, Zhou Y, Duan H . Porous Co-C Core-Shell Nanocomposites Derived from Co-MOF-74 with Enhanced Electromagnetic Wave Absorption Performance. ACS Appl Mater Interfaces. 2018; 10(13):11333-11342. DOI: 10.1021/acsami.8b00965. View

12.

Lu Y, Wang Y, Li H, Lin Y, Jiang Z, Xie Z . MOF-Derived Porous Co/C Nanocomposites with Excellent Electromagnetic Wave Absorption Properties. ACS Appl Mater Interfaces. 2015; 7(24):13604-11. DOI: 10.1021/acsami.5b03177. View

13.

Parsapour F, Moradi M, Bahadoran A . Metal-organic frameworks-derived layered double hydroxides: From controllable synthesis to various electrochemical energy storage/conversion applications. Adv Colloid Interface Sci. 2023; 313:102865. DOI: 10.1016/j.cis.2023.102865. View

14.

Wang L, Zhu S, Zhu J . Constructing ordered macropores in hollow Co/C polyhedral nanocages shell toward superior microwave absorbing performance. J Colloid Interface Sci. 2022; 624:423-432. DOI: 10.1016/j.jcis.2022.05.158. View

15.

Huang Y, Xue W, Hou X, Zhao R . Metal Oxide/Nitrogen-Doped Carbon Nanosheet Heteronanostructures as Highly Efficient Electromagnetic Wave Absorbing Materials. Molecules. 2021; 26(24). PMC: 8708817. DOI: 10.3390/molecules26247537. View

16.

Li J, Wu Q, Wang X, Wang B, Liu T . Metal-organic framework-derived Co/CoO nanoparticles with tunable particle size for strong low-frequency microwave absorption in the S and C bands. J Colloid Interface Sci. 2022; 628(Pt A):10-21. DOI: 10.1016/j.jcis.2022.07.138. View

17.

Jiao Z, Hu J, Ma M, Liu Y, Zhao J, Wang X . One-dimensional core-shell CoC@CoFe/C@PPy composites for high-efficiency microwave absorption. J Colloid Interface Sci. 2023; 650(Pt B):2014-2023. DOI: 10.1016/j.jcis.2023.07.072. View

18.

Bi Y, Ma M, Liu Y, Tong Z, Wang R, Chung K . Microwave absorption enhancement of 2-dimensional CoZn/C@MoS@PPy composites derived from metal-organic framework. J Colloid Interface Sci. 2021; 600:209-218. DOI: 10.1016/j.jcis.2021.04.137. View

19.

Guo Y, Wang D, Wang J, Tian Y, Liu H, Liu C . Hierarchical HCF@NC/Co Derived from Hollow Loofah Fiber Anchored with Metal-Organic Frameworks for Highly Efficient Microwave Absorption. ACS Appl Mater Interfaces. 2021; 14(1):2038-2050. DOI: 10.1021/acsami.1c21396. View

20.

Imran M, Zouli N, Ahamad T, Alshehri S, Chandan M, Hussain S . Carbon-coated FeO core-shell super-paramagnetic nanoparticle-based ferrofluid for heat transfer applications. Nanoscale Adv. 2022; 3(7):1962-1975. PMC: 9418956. DOI: 10.1039/d1na00061f. View