Revealing the Na Storage Behavior of Graphite Anodes in Low-concentration Imidazole-based Electrolytes

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2024 May 3

PMID 38699262

Authors

Wei Zhao

Chunting Wang

Zhenjie Cheng

Cheng Zheng

Qian Yao

Jun Pan

Xiaojian Ma

Jian Yang

Affiliations

Soon will be listed here.

Abstract

The thermodynamic instability of Na-intercalated compounds is an important factor limiting the application of graphite anodes in sodium-ion batteries. Although solvent co-intercalation is recognized as a simple and effective strategy, the challenge lies in the lack of durable electrolytes. Herein, we successfully apply low-concentration imidazole-based electrolytes to graphite anodes for sodium-ion batteries. Specifically, low concentrations ensure high ionic conductivity while saving on costs. Methylimidazole molecules can be co-intercalated with Na, and a small amount of unreleased solvated Na serves the dual purpose of providing support to the graphite layer and preventing peeling off. The interphase formed in imidazole is more uniform and dense compared with that in ether electrolytes, which reduces side reactions and the risk of internal short circuits. The obtained battery demonstrates a long cycle life of 1800 cycles with a capacity retention of 84.6%. This success extends to other imidazole-based solvents such as 1-propylimidazole and 1-butylimidazole.

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