» Articles » PMID: 38680379

Guided Design of Efficient Oxygen Evolution Catalysts Using Patent Analysis

Overview
Journal ACS Omega
Specialty Chemistry
Date 2024 Apr 29
PMID 38680379
Authors
Affiliations
Soon will be listed here.
Abstract

The facile and rapid design of efficient oxygen evolution reaction (OER) catalysts holds paramount significance for energy conversion devices, such as water electrolyzers and fuel cells. Despite substantial progress in catalyst synthesis and performance exploration, the design and selection processes remain inefficient. In this context, we integrate patent analysis with catalyst design, leveraging the scholarly research functionalities within patent analyses to aid in the design and synthesis of a NiFeRu-carbon catalyst as a high-performance OER catalyst. The results demonstrate that the NiFeRu-Carbon catalyst with low Ru loading (0.3 wt %) exhibits an overpotential of only 219 mV at 10 mA cm under alkaline conditions, and after continuous operation for 200 h, the overpotential only attenuates by 15 mV. The incorporation of high-valence Ru dopants elevated the intrinsic activity of individual catalytic sites within NiFe-layered double hydroxides (LDHs). During the catalytic process, the partial dissolution of Ru might lead to the generation of numerous oxygen vacancies within NiFe- LDH, thereby enhancing the catalyst's activity and stability.

References
1.
Wang H, Li X, Ruan Q, Tang J . Ru and RuO decorated carbon nitride for efficient ammonia photosynthesis. Nanoscale. 2020; 12(23):12329-12335. DOI: 10.1039/d0nr02527e. View

2.
Barcelon Yang C . Role of patent analysis in corporate R&D. Pharm Pat Anal. 2013; 1(1):5-7. DOI: 10.4155/ppa.12.1. View

3.
Wu Z, Zou Z, Huang J, Gao F . NiFeO Nanoparticles/NiFe Layered Double-Hydroxide Nanosheet Heterostructure Array for Efficient Overall Water Splitting at Large Current Densities. ACS Appl Mater Interfaces. 2018; 10(31):26283-26292. DOI: 10.1021/acsami.8b07835. View

4.
Wang Y, Zhao Y, Liu L, Qin W, Liu S, Tu J . Mesoporous Single Crystals with Fe-Rich Skin for Ultralow Overpotential in Oxygen Evolution Catalysis. Adv Mater. 2022; 34(20):e2200088. DOI: 10.1002/adma.202200088. View

5.
Li Q, Huang F, Li S, Zhang H, Yu X . Oxygen Vacancy Engineering Synergistic with Surface Hydrophilicity Modification of Hollow Ru Doped CoNi-LDH Nanotube Arrays for Boosting Hydrogen Evolution. Small. 2021; 18(2):e2104323. DOI: 10.1002/smll.202104323. View