Reticular Chemistry Guided Precise Construction of Zirconium-pentacarboxylate Frameworks with 5-connected Zr Clusters

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2024 Mar 1

PMID 38425507

Authors

Tianyou Peng

Chao-Qin Han

Hai-Lun Xia

Kang Zhou

Jian Zhang

Jincheng Si

Lei Wang

Jiafeng Miao

Fu-An Guo

Hao Wang

Lu-Lu Qu

Guozhong Xu

Jing Li

Xiao-Yuan Liu

Affiliations

Soon will be listed here.

Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) have been extensively studied due to their very rich structural chemistry. The combination of nearly unlimited carboxylic acid-based linkers and Zr clusters with multiple connectivities has led to diverse structures and specific properties of resultant Zr-MOFs. Herein, we demonstrate the successful use of reticular chemistry to construct two novel Zr-MOFs, HIAM-4040 and HIAM-4040-OH, with zfu topology. Based on a thorough structural analysis of (4,4)-connected lvt-type Zr-tetracarboxylate frameworks and a judicious linker design, we have obtained the first example of a Zr-pentacarboxylate framework featuring unprecedented 5-connected organic linkers and 5-connected Zr clusters. Compared with HIAM-4040, a larger Stokes shift is achieved in HIAM-4040-OH hydroxyl group induced excited-state intramolecular proton transfer (ESIPT). HIAM-4040-OH exhibits high chemical and thermal stability and is used for HClO detection in aqueous solution with excellent sensitivity and selectivity.

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