A Novel Threefold Interpenetrated Zirconium Metal-organic Framework Exhibiting Separation Ability for Strong Acids

Overview

Journal Chem Sci

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2024 Jan 26

PMID 38274054

Authors

Kyoko Shiraishi

Kazuya Otsubo

Kenichi Kato

Masaaki Sadakiyo

Affiliations

Soon will be listed here.

Abstract

We report on the synthesis and selective adsorption property of a novel threefold interpenetrated Zr-based metal-organic framework (MOF), [ZrO(OH)(HCOO)(BPT)] (BPT = [1,1'-biphenyl]-3,4',5-tricarboxylate) (abbreviated as Zr-BPT). This MOF shows a high tolerance to acidic conditions and has permanent pores, the size of which (approx. <5.6 Å) is the smallest ever reported among porous Zr-based MOFs with high acid tolerance. Zr-BPT selectively adsorbs aryl acids due to its strong affinity for them and exhibits separation ability, even between strong acid molecules, such as sulfonic and phosphonic acids. This is the first demonstration of a MOF exhibiting selective adsorption and separation ability for strong acids.

Citing Articles

Selective Separation of C Aromatics by an Interpenetrating Metal-Organic Framework Material.

Sun N, Zhou X, Yu H, Si X, Ding F, Sun Y Inorg Chem. 2024; 63(40):18847-18854.

PMID: 39327973 PMC: 11462495. DOI: 10.1021/acs.inorgchem.4c02969.

References

Foo M, Matsuda R, Hijikata Y, Krishna R, Sato H, Horike S . An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO2 over C2H2. J Am Chem Soc. 2016; 138(9):3022-30. DOI: 10.1021/jacs.5b10491. View

Chunsrivirot S, Trout B . Free energy of binding of a small molecule to an amorphous polymer in a solvent. Langmuir. 2011; 27(11):6910-9. DOI: 10.1021/la201011q. View

Cui W, Hu T, Bu X . Metal-Organic Framework Materials for the Separation and Purification of Light Hydrocarbons. Adv Mater. 2019; 32(3):e1806445. DOI: 10.1002/adma.201806445. View

Dutta S, Let S, Sharma S, Mahato D, Ghosh S . Recognition and Sequestration of Toxic Inorganic Water Pollutants with Hydrolytically Stable Metal-Organic Frameworks. Chem Rec. 2021; 21(7):1666-1680. DOI: 10.1002/tcr.202100127. View

Duan Z, Li Y, Xiao X, Huang X, Li X, Li Y . Interpenetrated Metal-Organic Frameworks with Topology and Versatile Functions. ACS Appl Mater Interfaces. 2020; 12(16):18715-18722. DOI: 10.1021/acsami.0c03336. View

Nguyen V, Deferm C, Caytan W, Riano S, Jones P, Binnemans K . Conversion of Lithium Chloride into Lithium Hydroxide by Solvent Extraction. J Sustain Metall. 2023; 9(1):107-122. PMC: 10015601. DOI: 10.1007/s40831-022-00629-2. View

Zhang Y, Zhang X, Lyu J, Otake K, Wang X, Redfern L . A Flexible Metal-Organic Framework with 4-Connected Zr Nodes. J Am Chem Soc. 2018; 140(36):11179-11183. DOI: 10.1021/jacs.8b06789. View

Liang B, Zhang X, Xie Y, Lin R, Krishna R, Cui H . An Ultramicroporous Metal-Organic Framework for High Sieving Separation of Propylene from Propane. J Am Chem Soc. 2020; 142(41):17795-17801. PMC: 10493866. DOI: 10.1021/jacs.0c09466. View

Kitagawa S, Kitaura R, Noro S . Functional porous coordination polymers. Angew Chem Int Ed Engl. 2004; 43(18):2334-75. DOI: 10.1002/anie.200300610. View

10.

Luo H, Ren Q, Wang P, Zhang J, Wang L, Ren X . High Proton Conductivity Achieved by Encapsulation of Imidazole Molecules into Proton-Conducting MOF-808. ACS Appl Mater Interfaces. 2019; 11(9):9164-9171. DOI: 10.1021/acsami.9b01075. View

11.

Kato K, Tanaka Y, Yamauchi M, Ohara K, Hatsui T . A statistical approach to correct X-ray response non-uniformity in microstrip detectors for high-accuracy and high-resolution total-scattering measurements. J Synchrotron Radiat. 2019; 26(Pt 3):762-773. PMC: 6510202. DOI: 10.1107/S1600577519002145. View

12.

Morris W, Volosskiy B, Demir S, Gandara F, McGrier P, Furukawa H . Synthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks. Inorg Chem. 2012; 51(12):6443-5. DOI: 10.1021/ic300825s. View

13.

Ding M, Flaig R, Jiang H, Yaghi O . Carbon capture and conversion using metal-organic frameworks and MOF-based materials. Chem Soc Rev. 2019; 48(10):2783-2828. DOI: 10.1039/c8cs00829a. View

14.

Feng D, Chung W, Wei Z, Gu Z, Jiang H, Chen Y . Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination. J Am Chem Soc. 2013; 135(45):17105-10. DOI: 10.1021/ja408084j. View

15.

Furukawa H, Gandara F, Zhang Y, Jiang J, Queen W, Hudson M . Water adsorption in porous metal-organic frameworks and related materials. J Am Chem Soc. 2014; 136(11):4369-81. DOI: 10.1021/ja500330a. View

16.

Ding M, Cai X, Jiang H . Improving MOF stability: approaches and applications. Chem Sci. 2020; 10(44):10209-10230. PMC: 7069376. DOI: 10.1039/c9sc03916c. View

17.

Ma J . Catalytic asymmetric synthesis of alpha- and beta-amino phosphonic acid derivatives. Chem Soc Rev. 2006; 35(7):630-6. DOI: 10.1039/b517100h. View

18.

Zhang Y, Zhang X, Chen Z, Otake K, Peterson G, Chen Y . A Flexible Interpenetrated Zirconium-Based Metal-Organic Framework with High Affinity toward Ammonia. ChemSusChem. 2020; 13(7):1710-1714. DOI: 10.1002/cssc.202000306. View

19.

Bloch W, Babarao R, Hill M, Doonan C, Sumby C . Post-synthetic structural processing in a metal-organic framework material as a mechanism for exceptional CO2/N2 selectivity. J Am Chem Soc. 2013; 135(28):10441-8. DOI: 10.1021/ja4032049. View

20.

Krause S, Hosono N, Kitagawa S . Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties. Angew Chem Int Ed Engl. 2020; 59(36):15325-15341. DOI: 10.1002/anie.202004535. View