Yolk-shell Structured Magnetic Mesoporous Organosilica Supported Ionic Liquid/Cu Complex: an Efficient Nanocatalyst for the Green Synthesis of Pyranopyrazoles

Overview

Journal Front Chem

Specialty Chemistry

Date 2023 Sep 25

PMID 37744055

Authors

Maryam Neysi

Dawood Elhamifar

Affiliations

Soon will be listed here.

Abstract

The preparation of yolk-shell structured magnetic mesoporous composites is a significant subject between researchers. Especially, modification of theses composites with ionic liquid/metal complex is very important for catalytic processes. In the present study, a novel magnetic methylene-based periodic mesoporous organosilica (PMO)-supported ionic liquid/Cu complex with yolk-shell structure (YS-FeO@PMO/IL-Cu) was prepared the soft template-assisted method. The TGA, FT-IR, SEM, EDX, XRD, VSM, nitrogen-sorption, and ICP techniques were employed to identify YS-FeO@PMO/IL-Cu. The YS-FeO@PMO/IL-Cu material was applied as a powerful nanocatalyst for the synthesis of pyranopyrazoles under ultrasonic media. The study demonstrated that the YS-FeO@PMO/IL-Cu nanocatalyst is highly recyclable, selective, and effective. The leaching test was performed to investigate the nature of the designed catalyst under the applied conditions.

Citing Articles

Magnetic yolk-shell structured periodic mesoporous organosilica supported palladium as a powerful and highly recoverable nanocatalyst for the reduction of nitrobenzenes.

Norouzi M, Elhamifar D, Kargar S Sci Rep. 2024; 14(1):16262.

PMID: 39009610 PMC: 11251011. DOI: 10.1038/s41598-024-66883-4.

Amine-containing yolk-shell structured magnetic organosilica nanocomposite as a highly efficient catalyst for the Knoevenagel reaction.

Neysi M, Elhamifar D Front Chem. 2024; 12:1336855.

PMID: 38380398 PMC: 10877015. DOI: 10.3389/fchem.2024.1336855.

References

Wang Y, Yang J, Chou S, Liu H, Zhang W, Zhao D . Uniform yolk-shell iron sulfide-carbon nanospheres for superior sodium-iron sulfide batteries. Nat Commun. 2015; 6:8689. PMC: 4846313. DOI: 10.1038/ncomms9689. View

Zhao X, Mendoza Sanchez B, Dobson P, Grant P . The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices. Nanoscale. 2011; 3(3):839-55. DOI: 10.1039/c0nr00594k. View

Zhang Q, Lee I, Joo J, Zaera F, Yin Y . Core-shell nanostructured catalysts. Acc Chem Res. 2012; 46(8):1816-24. DOI: 10.1021/ar300230s. View

Yu L, Pan P, Zhang Y, Zhang Y, Wan L, Cheng X . Nonsacrificial Self-Template Synthesis of Colloidal Magnetic Yolk-Shell Mesoporous Organosilicas for Efficient Oil/Water Interface Catalysis. Small. 2019; 15(14):e1805465. DOI: 10.1002/smll.201805465. View

Neysi M, Elhamifar D . Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst. Sci Rep. 2022; 12(1):7970. PMC: 9106672. DOI: 10.1038/s41598-022-11918-x. View

Du X, He J . Spherical silica micro/nanomaterials with hierarchical structures: synthesis and applications. Nanoscale. 2011; 3(10):3984-4002. DOI: 10.1039/c1nr10660k. View

Liu J, Xu J, Che R, Chen H, Liu M, Liu Z . Hierarchical Fe3O4@TiO2 yolk-shell microspheres with enhanced microwave-absorption properties. Chemistry. 2013; 19(21):6746-52. DOI: 10.1002/chem.201203557. View

Morishita M, Shiraishi Y, Hirai T . Ti-containing mesoporous organosilica as a photocatalyst for selective olefin epoxidation. J Phys Chem B. 2006; 110(36):17898-905. DOI: 10.1021/jp062355w. View

Liu J, Qiao S, Chen J, Lou X, Xing X, Lu G . Yolk/shell nanoparticles: new platforms for nanoreactors, drug delivery and lithium-ion batteries. Chem Commun (Camb). 2011; 47(47):12578-91. DOI: 10.1039/c1cc13658e. View

10.

Yin Y, Rioux R, Erdonmez C, Hughes S, Somorjai G, Alivisatos A . Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science. 2004; 304(5671):711-4. DOI: 10.1126/science.1096566. View

11.

Purbia R, Paria S . A simple turn on fluorescent sensor for the selective detection of thiamine using coconut water derived luminescent carbon dots. Biosens Bioelectron. 2016; 79:467-75. DOI: 10.1016/j.bios.2015.12.087. View

12.

Neysi M, Elhamifar D . Magnetic ethylene-based periodic mesoporous organosilica supported palladium: An efficient and recoverable nanocatalyst for Suzuki reaction. Front Chem. 2023; 11:1112911. PMC: 9933923. DOI: 10.3389/fchem.2023.1112911. View

13.

Puanngam M, Unob F . Preparation and use of chemically modified MCM-41 and silica gel as selective adsorbents for Hg(II) ions. J Hazard Mater. 2007; 154(1-3):578-87. DOI: 10.1016/j.jhazmat.2007.10.090. View

14.

Gao J, Liang G, Zhang B, Kuang Y, Zhang X, Xu B . FePt@CoS(2) yolk-shell nanocrystals as a potent agent to kill HeLa cells. J Am Chem Soc. 2007; 129(5):1428-33. DOI: 10.1021/ja067785e. View

15.

Elhamifar D, Mofatehnia P, Faal M . Magnetic nanoparticles supported Schiff-base/copper complex: An efficient nanocatalyst for preparation of biologically active 3,4-dihydropyrimidinones. J Colloid Interface Sci. 2017; 504:268-275. DOI: 10.1016/j.jcis.2017.05.044. View

16.

Kamata K, Lu Y, Xia Y . Synthesis and characterization of monodispersed core-shell spherical colloids with movable cores. J Am Chem Soc. 2003; 125(9):2384-5. DOI: 10.1021/ja0292849. View