» Articles » PMID: 37671004

Controlled Synthesis of MoC Micron Flowers Vapor-liquid-solid Method As Enhanced Electrocatalyst for Hydrogen Evolution Reaction

Overview
Journal RSC Adv
Specialty Chemistry
Date 2023 Sep 6
PMID 37671004
Authors
Affiliations
Soon will be listed here.
Abstract

MoC demonstrates excellent performance in catalysis, and it has been found to possess excellent hydrogen evolution reaction (HER) catalytic activity and highly efficient nitrogen fixation. The catalytic activity of MoC is greatly influenced and restricted by the preparation method. Sintering and carbon deposition, which affect the catalytic activity of MoC, are inevitable in the traditional vapor-solid-solid (VSS) process. In this study, we report the controllable synthesis of α-MoC micron flowers by adjusting the growth temperature a vapor-liquid-solid (VLS) process. The density of the MoC micron flowers is closely related to the concentration of NaMoO aqueous solution. The as-grown MoC micron flowers dispersed with Pt are validated to be an enhanced collaborative electrocatalyst for HER against Pt/VSS-MoC.

References
1.
Gao Q, Zhao X, Xiao Y, Zhao D, Cao M . A mild route to mesoporous Mo2C-C hybrid nanospheres for high performance lithium-ion batteries. Nanoscale. 2014; 6(11):6151-7. DOI: 10.1039/c3nr06678a. View

2.
Liu H, Qi G, Tang C, Chen M, Chen Y, Shu Z . Growth of Large-Area Homogeneous Monolayer Transition-Metal Disulfides via a Molten Liquid Intermediate Process. ACS Appl Mater Interfaces. 2020; 12(11):13174-13181. DOI: 10.1021/acsami.9b22397. View

3.
Feng S, Tan J, Zhao S, Zhang S, Khan U, Tang L . Synthesis of Ultrahigh-Quality Monolayer Molybdenum Disulfide through In Situ Defect Healing with Thiol Molecules. Small. 2020; 16(35):e2003357. DOI: 10.1002/smll.202003357. View

4.
Lin L, Yu Q, Peng M, Li A, Yao S, Tian S . Atomically Dispersed Ni/α-MoC Catalyst for Hydrogen Production from Methanol/Water. J Am Chem Soc. 2020; 143(1):309-317. DOI: 10.1021/jacs.0c10776. View

5.
Li S, Lin Y, Liu X, Hu Z, Wu J, Nakajima H . Wafer-scale and deterministic patterned growth of monolayer MoSvia vapor-liquid-solid method. Nanoscale. 2019; 11(34):16122-16129. DOI: 10.1039/c9nr04612g. View