» Articles » PMID: 37601241

Chemical Recycling of Polyolefins: a Closed-loop Cycle of Waste to Olefins

Overview
Journal Natl Sci Rev
Date 2023 Aug 21
PMID 37601241
Authors
Affiliations
Soon will be listed here.
Abstract

The unsuitable disposal of plastic wastes has caused serious environmental pollution, and finding a green manner to address this problem has aroused wide concern. Plastic wastes, especially polyolefin wastes, are rich in carbon and hydrogen, and chemical recycling shows distinct advantages in their conversion into olefins and realizes a closed-loop cycling of plastic wastes. Plastic wastes should be labeled before disposal. The necessity for, and methods of, pretreatment are introduced in this paper and the whole recycling process of polyolefin wastes is also summarized. As the core technology pyrolysis, including thermal, catalytic and solvolysis processes, is introduced in detail due to its potential for future development. We also briefly describe the feasible strategies of pyrolytic oil refining and life cycle assessment of the chemical recycling process. In addition, suggestions and perspectives concerning the industrial improvement of polyolefin chemical recycling are proposed.

Citing Articles

Recent Progress in Polyolefin Plastic: Polyethylene and Polypropylene Transformation and Depolymerization Techniques.

de Souza A, Ferreira P, de Jesus I, de Oliveira R, de Carvalho A, Futuro D Molecules. 2025; 30(1.

PMID: 39795145 PMC: 11721993. DOI: 10.3390/molecules30010087.


Electrochemical recycling of polymeric materials.

Zhang W, Killian L, Thevenon A Chem Sci. 2024; 15(23):8606-8624.

PMID: 38873080 PMC: 11168094. DOI: 10.1039/d4sc01754d.


Ni-based catalysts supported on Hbeta zeolite for the hydrocracking of waste polyolefins.

Zhang G, Mao Q, Yue Y, Gao R, Duan Y, Du H RSC Adv. 2024; 14(23):15856-15861.

PMID: 38756856 PMC: 11096778. DOI: 10.1039/d4ra02809k.


Coupled conversion of polyethylene and carbon dioxide catalyzed by a zeolite-metal oxide system.

Liu Y, Ma B, Tian J, Zhao C Sci Adv. 2024; 10(15):eadn0252.

PMID: 38608025 PMC: 11014447. DOI: 10.1126/sciadv.adn0252.


Ductile Copolyesters Prepared Using Succinic Acid, 1,4-Butanediol, and Bis(2-hydroxyethyl) Terephthalate with Minimizing Generation of Tetrahydrofuran.

Park S, Seo H, Seo Y, Park J, Kim H, Cho W Polymers (Basel). 2024; 16(4).

PMID: 38399897 PMC: 10891720. DOI: 10.3390/polym16040519.


References
1.
Jia X, Qin C, Friedberger T, Guan Z, Huang Z . Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions. Sci Adv. 2016; 2(6):e1501591. PMC: 4928905. DOI: 10.1126/sciadv.1501591. View

2.
Hahladakis J, Velis C, Weber R, Iacovidou E, Purnell P . An overview of chemical additives present in plastics: Migration, release, fate and environmental impact during their use, disposal and recycling. J Hazard Mater. 2017; 344:179-199. DOI: 10.1016/j.jhazmat.2017.10.014. View

3.
Zanella D, Romagnoli M, Malcangi S, Beccaria M, Chenet T, De Luca C . The contribution of high-resolution GC separations in plastic recycling research. Anal Bioanal Chem. 2023; 415(13):2343-2355. PMC: 10149442. DOI: 10.1007/s00216-023-04519-8. View

4.
Matjasic T, Simcic T, Medvescek N, Bajt O, Dreo T, Mori N . Critical evaluation of biodegradation studies on synthetic plastics through a systematic literature review. Sci Total Environ. 2020; 752:141959. DOI: 10.1016/j.scitotenv.2020.141959. View

5.
Zhang W, Kim S, Wahl L, Khare R, Hale L, Hu J . Low-temperature upcycling of polyolefins into liquid alkanes via tandem cracking-alkylation. Science. 2023; 379(6634):807-811. DOI: 10.1126/science.ade7485. View