Effect of Zwitterionic Additive on Electrode Protection Through Electrochemical Performances of Anatase TiO Nanotube Array Electrode in Ionic Liquid Electrolyte

Overview

Journal Int J Mol Sci

Publisher MDPI

Specialties Biochemistry
Chemistry
Molecular Biology

Date 2023 Feb 25

PMID 36834905

Authors

Aleksandra Roganovic

Milan Vranes

Nikola Cvjeticanin

Xiaoping Chen

Snezana Papovic

Affiliations

Soon will be listed here.

Abstract

In this work, a functionalized zwitterionic (ZI) compound 1-butylsulfonate-3-methylimidazole (CCimSO) was synthesized and tested as an additive to LiTFSI/CCimTFSI ionic liquid-based electrolytes for lithium-ion batteries. The structure and purity of CCimSO were confirmed by NMR and FTIR spectroscopy. The thermal stability of the pure CCimSO was examined by simultaneous thermogravimetric-mass spectrometric (TG-MS) measurements and differential scanning calorimetry (DSC). The LiTFSI/CCimTFSI/CCimSO system was tested as a potential electrolyte for lithium-ion batteries by using anatase TiO nanotube array electrode as the anode material. This electrolyte with 3% CCimSO showed significant improvement of lithium-ion intercalation/deintercalation properties, such as capacity retention and Coulombic efficiency compared to electrolyte without additive.

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