Dual Stimuli-responsive Phosphorescence of a Pb(II) Coordination Polymer to Acidic Vapors and Thermal Treatment

We present a new intensely phosphorescent Pb(II) coordination polymer (1) containing a heteroatomic ligand. It has a quantum yield of 21.62% and a lifetime of 25.46 μs. The naked-eye solid-state photoluminescence of 1 significantly changes in response to acidic vapors and thermal treatment, indicating the coexistence of acidochromic and thermochromic luminescence.