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Electronic Transmutation Concept: Is the Inverse Process Possible? An Evaluation of Main Group Compounds

Overview
Journal ACS Omega
Specialty Chemistry
Date 2023 Jan 30
PMID 36713707
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Abstract

The electronic transmutation (ET) concept states that when an element with atomic number gains an electron, it transmutes into a + 1 element, leading to species that possess similar chemical bonding patterns and geometric structures regarding the original ( + 1) element. In this work, the opposite concept, that is, the inverse ET, is assessed. For this purpose, several main group compounds have been analyzed in terms of the adaptive natural density partitioning. The obtained results suggest that when an atom loses an electron, it transmutes into a - 1 atom, acquiring its geometrical structure and bonding pattern.

References
1.
Rasul G, Prakash G, Olah G . Comparative ab initio study of the structures and stabilities of the ethane dication C2H6(2+) and its silicon analogues Si2H6(2+) and CSiH6(2+). J Phys Chem A. 2006; 109(5):798-801. DOI: 10.1021/jp0404652. View

2.
Glendening E, Landis C, Weinhold F . NBO 6.0: natural bond orbital analysis program. J Comput Chem. 2013; 34(16):1429-37. DOI: 10.1002/jcc.23266. View

3.
Carion R, Champagne B, Monaco G, Zanasi R, Pelloni S, Lazzeretti P . Ring Current Model and Anisotropic Magnetic Response of Cyclopropane. J Chem Theory Comput. 2015; 6(7):2002-18. DOI: 10.1021/ct100175j. View

4.
Lundell K, Zhang X, Boldyrev A, Bowen K . The Existence of a Designer Al=Al Double Bond in the LiAl H Cluster Formed by Electronic Transmutation. Angew Chem Int Ed Engl. 2017; 56(52):16593-16596. DOI: 10.1002/anie.201710338. View

5.
Zhang X, Popov I, Lundell K, Wang H, Mu C, Wang W . Realization of an Al≡Al Triple Bond in the Gas-Phase Na Al Cluster via Double Electronic Transmutation. Angew Chem Int Ed Engl. 2018; 57(43):14060-14064. DOI: 10.1002/anie.201806917. View