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Double Boron-embedded Multiresonant Thermally Activated Delayed Fluorescent Materials for Organic Light-emitting Diodes

Overview
Journal Commun Chem
Publisher Springer Nature
Specialty Chemistry
Date 2023 Jan 25
PMID 36698018
Authors
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Abstract

The subclass of multi resonant thermally activated delayed fluorescent emitters (MR-TADF) containing boron atoms has garnered significant attention in the field of organic light emitting diode (OLED) research. Among boron-based MR-TADF emitters, double boron-embedded MR-TADF (DB-MR-TADF) emitters show excellent electroluminescence performances with high photoluminescence quantum yields, narrow band emission, and beneficially small singlet-triplet energy levels in all the full-color gamut regions. This article reviews recent progress in DB-MR-TADF emitters, with particular attention to molecular design concepts, synthetic routes, optoelectronic properties, and OLED performance, giving future prospects for real-world applications.

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References
1.
Hatakeyama T, Shiren K, Nakajima K, Nomura S, Nakatsuka S, Kinoshita K . Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO-LUMO Separation by the Multiple Resonance Effect. Adv Mater. 2016; 28(14):2777-81. DOI: 10.1002/adma.201505491. View

2.
Chen C, Du C, Wang X . The Rise of 1,4-BN-Heteroarenes: Synthesis, Properties, and Applications. Adv Sci (Weinh). 2022; 9(19):e2200707. PMC: 9259729. DOI: 10.1002/advs.202200707. View

3.
Hosokai T, Matsuzaki H, Nakanotani H, Tokumaru K, Tsutsui T, Furube A . Evidence and mechanism of efficient thermally activated delayed fluorescence promoted by delocalized excited states. Sci Adv. 2017; 3(5):e1603282. PMC: 5425233. DOI: 10.1126/sciadv.1603282. View

4.
Park J, Lim J, Lee J, Jang B, Han J, Yoon S . Asymmetric Blue Multiresonance TADF Emitters with a Narrow Emission Band. ACS Appl Mater Interfaces. 2021; 13(38):45798-45805. DOI: 10.1021/acsami.1c11399. View

5.
Uoyama H, Goushi K, Shizu K, Nomura H, Adachi C . Highly efficient organic light-emitting diodes from delayed fluorescence. Nature. 2012; 492(7428):234-8. DOI: 10.1038/nature11687. View