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Thin Polymer Films by Oxidative or Reductive Electropolymerization and Their Application in Electrochromic Windows and Thin-Film Sensors

Overview
Journal Molecules
Publisher MDPI
Specialty Biology
Date 2023 Jan 21
PMID 36677941
Authors
Affiliations
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Abstract

Electrically conducting and semiconducting polymers represent a special and still very attractive class of functional chromophores, especially due to their unique optical and electronic properties and their broad device application potential. They are potentially suitable as materials for several applications of high future relevance, for example flexible photovoltaic modules, components of displays/screens and batteries, electrochromic windows, or photocatalysts. Therefore, their synthesis and structure elucidation are still intensely investigated. This article will demonstrate the very fruitful interplay of current electropolymerization research and its exploitation for science education issues. Experiments involving the synthesis of conducting polymers and their assembly into functional devices can be used to teach basic chemical and physical principles as well as to motivate students for an innovative and interdisciplinary field of chemistry.

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References
1.
Tajik S, Beitollahi H, Garkani Nejad F, Shoaie I, Khalilzadeh M, Shahedi Asl M . Recent developments in conducting polymers: applications for electrochemistry. RSC Adv. 2022; 10(62):37834-37856. PMC: 9057190. DOI: 10.1039/d0ra06160c. View

2.
Turbiez M, Frere P, Allain M, Videlot C, Ackermann J, Roncali J . Design of organic semiconductors: tuning the electronic properties of pi-conjugated oligothiophenes with the 3,4-ethylenedioxythiophene (EDOT) building block. Chemistry. 2005; 11(12):3742-52. DOI: 10.1002/chem.200401058. View

3.
Palma-Cando A, Scherf U . Electrogenerated thin films of microporous polymer networks with remarkably increased electrochemical response to nitroaromatic analytes. ACS Appl Mater Interfaces. 2015; 7(21):11127-33. DOI: 10.1021/acsami.5b02233. View

4.
Sharma P, Pietrzyk-Le A, DSouza F, Kutner W . Electrochemically synthesized polymers in molecular imprinting for chemical sensing. Anal Bioanal Chem. 2012; 402(10):3177-204. PMC: 3303047. DOI: 10.1007/s00216-011-5696-6. View

5.
Han L, Bao X, Hu T, Du Z, Chen W, Zhu D . Novel donor-acceptor polymer containing 4,7-bis(thiophen-2-yl)benzo[c][1,2,5]thiadiazole for polymer solar cells with power conversion efficiency of 6.21%. Macromol Rapid Commun. 2014; 35(12):1153-7. DOI: 10.1002/marc.201400036. View