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Functional Separators for Long-Life and Safe Li Metal Batteries: A Minireview

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Publisher MDPI
Date 2022 Nov 11
PMID 36365540
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Abstract

Lithium (Li) metal batteries (LMBs) have received extensive research attention in recent years because of their high energy density. However, uncontrollable Li dendrite growth deteriorates the battery life and brings about severe safety hazards. The rational design of battery separators is an effective approach to regulate uniform Li metal deposition towards boosted cycle life and safety of LMBs. Herein, we review the recent research progress concerning this issue, including mechanically strengthened separator fabrication, functional separator construction towards regulated Li ion deposition, and flame-retardant separator design. Moreover, the key issues and prospects of optimal design of separators are clarified for future development. This minireview is expected to bring new insight into developing advanced separators for long-life and safe LMBs.

References
1.
Wen K, Liu L, Chen S, Zhang S . A bidirectional growth mechanism for a stable lithium anode by a platinum nanolayer sputtered on a polypropylene separator. RSC Adv. 2022; 8(23):13034-13039. PMC: 9079675. DOI: 10.1039/c8ra02140f. View

2.
Wang Z, Wang Y, Wu C, Pang W, Mao J, Guo Z . Constructing nitrided interfaces for stabilizing Li metal electrodes in liquid electrolytes. Chem Sci. 2021; 12(26):8945-8966. PMC: 8261733. DOI: 10.1039/d1sc01806j. View

3.
Pei F, Fu A, Ye W, Peng J, Fang X, Wang M . Robust Lithium Metal Anodes Realized by Lithiophilic 3D Porous Current Collectors for Constructing High-Energy Lithium-Sulfur Batteries. ACS Nano. 2019; 13(7):8337-8346. DOI: 10.1021/acsnano.9b03784. View

4.
Wu H, Zhuo D, Kong D, Cui Y . Improving battery safety by early detection of internal shorting with a bifunctional separator. Nat Commun. 2014; 5:5193. DOI: 10.1038/ncomms6193. View

5.
Zeng G, Zhao J, Feng C, Chen D, Meng Y, Boateng B . Flame-Retardant Bilayer Separator with Multifaceted van der Waals Interaction for Lithium-Ion Batteries. ACS Appl Mater Interfaces. 2019; 11(29):26402-26411. DOI: 10.1021/acsami.9b08553. View