Highly Emissive Planarized ,-diarylated Benzonaphthoazaborine Compounds for Narrowband Blue Fluorescence

Highly fluorescent blue emitters with high color purity are of great significance for optical applications. Herein, a series of planarized ,-diarylated benzonaphthoazaborine compounds, namely, BzNp (1), BuBzNp (2), BuBzNp (3), BuBzMeNp (4), and BuBzBuNp (5), where electron-donating Bu and Me groups are differently introduced into the -Ph, -Ph, or benzoazaborine rings, are prepared and characterized. All compounds exhibit low-energy absorptions ( = 462-467 nm) and emissions ( = 472-478 nm) remarkably red-shifted compared with those found for the pristine dibenzoazaborine compound (404 and 415 nm, respectively). Although the expansion of π-conjugation in the azaborine ring by replacing one phenyl ring with a naphthyl ring is mainly responsible for the redshifts, the emission is also fine-tuned by attached alkyl groups, which have a greater impact on the B-centered LUMO level at the azaborine ring than at the -Ph ring. The bandgap control and emission tuning are further supported by electrochemical and theoretical studies. Notably, blue to sky-blue fluorescence of all compounds exhibits unitary photoluminescence quantum yields, narrow full width at half maximum values (∼20 nm), and small Stokes shifts (∼11 nm), indicating strong emissions with high color purity.