Adsorption of Magenta Dye on PbO Doped MgZnO: Interpretation of Statistical Physics Parameters Using Double-Layer Models

Overview

Journal Int J Environ Res Public Health

Publisher MDPI

Specialties Environmental Health
Public Health

Date 2022 Oct 14

PMID 36231501

Authors

Tariq Altalhi

Ganesh Jethave

Umesh Fegade

Gaber A M Mersal

Mohamed M Ibrahim

M H H Mahmoud

Tushar Kumeria

Kalpesh A Isai

Milind Sonawane

Affiliations

Soon will be listed here.

Abstract

This article reports the synthesis of PbO doped MgZnO (PbO@MgZnO) by a co-precipitation method, followed by an ultrasonication process. PbO@MgZnO demonstrates a significant adsorption capability toward Magenta Dye (MD). The greatest adsorption capability was optimized by varying parameters such as pH, MD concentration, and adsorbent dose. The kinetics study illustrates that the adsorption of MD on PbO@MgZnO follows the pseudo-second-order. The isotherm study revealed that Langmuir is best fitted for the adsorption, but with little difference in the R value of Langmuir and Freundlich, the adsorption process cloud be single or multi-layer. The maximum adsorption capacity was found to be 333.33 mg/g. The negative ΔG refers to the spontaneity of MD adsorption on PbO@MgZnO. The steric parameters from statistical physics models also favor the multi-layer adsorption mechanism. As a function of solution temperature, the parameter pattern has values of = 0.395, 0.290, and 0.280 for 298, 308, and 318 K, respectively (i.e., all values were below 1). Therefore, horizontal molecule positioning and multiple locking mechanisms were implicated during interactions between MD and PbO@MgZnO active sites.

Citing Articles

Chitin-Based Magnesium Oxide Biocomposite for the Removal of Methyl Orange from Water.

Majdoubi H, Alqadami A, El Kaim Billah R, Otero M, Jeon B, Hannache H Int J Environ Res Public Health. 2023; 20(1).

PMID: 36613153 PMC: 9819834. DOI: 10.3390/ijerph20010831.

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