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Modulation of Z-scheme Photocatalysts for Pharmaceuticals Remediation and Pathogen Inactivation: Design Devotion, Concept Examination, and Developments

Overview
Journal Chem Eng J
Publisher Elsevier
Date 2022 Sep 5
PMID 36060035
Authors
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Abstract

The recent outbreak of Covid-19 guarantees overconsumption of different drugs as a necessity to reduce the symptoms caused by this pandemic. This triggers the proliferation of pharmaceuticals into drinking water systems. Is there any hope for access to safe drinking water? Photocatalytic degradation using artificial Z-scheme photocatalysts that has been employed for over a decade conveys a prospect for sustainable clean water supply. It is compelling to comprehensively summarise the state-of-the-art effects of Z-scheme photocatalytic systems towards the removal of pharmaceuticals in water. The principle of Z-scheme and the techniques used to validate the Z-scheme interfacial charge transfer are explored in detail. The application of the Z-scheme photocatalysts towards the degradation of antibiotics, NSAIDs, and bacterial/viral inactivation is deliberated. Conclusions and stimulating standpoints on the challenges of this emergent research direction are presented. The insights and up-to-date information will prompt the up-scaling of Z- scheme photocatalytic systems for commercialization.

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References
1.
Sjogren J, Sierka R . Inactivation of Phage MS2 by Iron-Aided Titanium Dioxide Photocatalysis. Appl Environ Microbiol. 1994; 60(1):344-7. PMC: 201311. DOI: 10.1128/aem.60.1.344-347.1994. View

2.
Liu J, Huang L, Li Y, Yang L, Wang C, Liu J . Construction of oxygen vacancy assisted Z-scheme BiO/BiOBr heterojunction for LED light pollutants degradation and bacteria inactivation. J Colloid Interface Sci. 2021; 600:344-357. DOI: 10.1016/j.jcis.2021.04.143. View

3.
Hill R, BENDALL F . Crystallization of a photosynthetic reductase from a green plant. Nature. 1960; 187:417. DOI: 10.1038/187417a0. View

4.
Habibi-Yangjeh A, Asadzadeh-Khaneghah S, Feizpoor S, Rouhi A . Review on heterogeneous photocatalytic disinfection of waterborne, airborne, and foodborne viruses: Can we win against pathogenic viruses?. J Colloid Interface Sci. 2020; 580:503-514. PMC: 7361121. DOI: 10.1016/j.jcis.2020.07.047. View

5.
Wen X, Qian-Lu , Lv X, Sun J, Guo J, Fei Z . Photocatalytic degradation of sulfamethazine using a direct Z-Scheme AgI/BiVO photocatalyst: Mineralization activity, degradation pathways and promoted charge separation mechanism. J Hazard Mater. 2019; 385:121508. DOI: 10.1016/j.jhazmat.2019.121508. View