Contribution of Configurations, Electrode and Membrane Materials, Electron Transfer Mechanisms, and Cost of Components on the Current and Future Development of Microbial Fuel Cells

Microbial fuel cells (MFCs) are a technology that can be applied to both the wastewater treatment and bioenergy generation. This work discusses the contribution of improvements regarding the configurations, electrode materials, membrane materials, electron transfer mechanisms, and materials cost on the current and future development of MFCs. Analysis of the most recent scientific publications on the field denotes that dual-chamber MFCs configuration offers the greatest potential due to the excellent ability to be adapted to different operating environments. Carbon-based materials show the best performance, biocompatibility of carbon-brush anode favors the formation of the biofilm in a mixed consortium and in wastewater as a substrate resembles the conditions of real scenarios. Carbon-cloth cathode modified with nanotechnology favors the conductive properties of the electrode. Ceramic clay membranes emerge as an interesting low-cost membrane with a proton conductivity of 0.0817 S cm, close to that obtained with the Nafion membrane. The use of nanotechnology in the electrodes also enhances electron transfer in MFCs. It increases the active sites at the anode and improves the interface with microorganisms. At the cathode, it favors its catalytic properties and the oxygen reduction reaction. These features together favor MFCs performance through energy production and substrate degradation with values above 2.0 W m and 90% respectively. All the recent advances in MFCs are gradually contributing to enable technological alternatives that, in addition to wastewater treatment, generate energy in a sustainable manner. It is important to continue the research efforts worldwide to make MFCs an available and affordable technology for industry and society.