Utilizing Nonpolar Organic Solvents for the Deposition of Metal-Halide Perovskite Films and the Realization of Organic Semiconductor/Perovskite Composite Photovoltaics

Overview

Journal ACS Energy Lett

Publisher American Chemical Society

Date 2022 May 13

PMID 35558900

Authors

Nakita K Noel

Bernard Wenger

Severin N Habisreutinger

Henry J Snaith

Affiliations

Soon will be listed here.

Abstract

Having captivated the research community with simple fabrication processes and staggering device efficiencies, perovskite-based optoelectronics are already on the way to commercialization. However, one potential obstacle to this commercialization is the almost exclusive use of toxic, highly coordinating, high boiling point solvents to make perovskite precursor inks. Herein, we demonstrate that nonpolar organic solvents, such as toluene, can be combined with butylamine to form an effective solvent for alkylammonium-based perovskites. Beyond providing broader solvent choice, our finding opens the possibility of blending perovskite inks with a wide range of previously incompatible materials, such as organic molecules, polymers, nanocrystals, and structure-directing agents. As a demonstration, using this solvent, we blend the perovskite ink with 6,6-phenyl-C-61-butyric acid methyl ester and show improved perovskite crystallization and device efficiencies. This processing route may enable a myriad of new possibilities for tuning the active layers in efficient photovoltaics, light-emitting diodes, and other semiconductor devices.

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References

Wojciechowski K, Leijtens T, Siprova S, Schlueter C, Horantner M, Wang J . C60 as an Efficient n-Type Compact Layer in Perovskite Solar Cells. J Phys Chem Lett. 2015; 6(12):2399-405. DOI: 10.1021/acs.jpclett.5b00902. View

Pang S, Zhou Y, Wang Z, Yang M, Krause A, Zhou Z . Transformative Evolution of Organolead Triiodide Perovskite Thin Films from Strong Room-Temperature Solid-Gas Interaction between HPbI3-CH3NH2 Precursor Pair. J Am Chem Soc. 2016; 138(3):750-3. DOI: 10.1021/jacs.5b11824. View

Lin Y, Bai Y, Fang Y, Chen Z, Yang S, Zheng X . Enhanced Thermal Stability in Perovskite Solar Cells by Assembling 2D/3D Stacking Structures. J Phys Chem Lett. 2018; 9(3):654-658. DOI: 10.1021/acs.jpclett.7b02679. View

Liu Z, Meng K, Wang X, Qiao Z, Xu Q, Li S . In Situ Observation of Vapor-Assisted 2D-3D Heterostructure Formation for Stable and Efficient Perovskite Solar Cells. Nano Lett. 2020; 20(2):1296-1304. DOI: 10.1021/acs.nanolett.9b04759. View

Ke W, Spanopoulos I, Stoumpos C, Kanatzidis M . Myths and reality of HPbI in halide perovskite solar cells. Nat Commun. 2018; 9(1):4785. PMC: 6235929. DOI: 10.1038/s41467-018-07204-y. View

Wang Z, McMeekin D, Sakai N, van Reenen S, Wojciechowski K, Patel J . Efficient and Air-Stable Mixed-Cation Lead Mixed-Halide Perovskite Solar Cells with n-Doped Organic Electron Extraction Layers. Adv Mater. 2016; 29(5). DOI: 10.1002/adma.201604186. View

Shao Y, Xiao Z, Bi C, Yuan Y, Huang J . Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells. Nat Commun. 2014; 5:5784. DOI: 10.1038/ncomms6784. View

Xu J, Buin A, Ip A, Li W, Voznyy O, Comin R . Perovskite-fullerene hybrid materials suppress hysteresis in planar diodes. Nat Commun. 2015; 6:7081. PMC: 4432582. DOI: 10.1038/ncomms8081. View

Saliba M, Matsui T, Seo J, Domanski K, Correa-Baena J, Nazeeruddin M . Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency. Energy Environ Sci. 2016; 9(6):1989-1997. PMC: 4936376. DOI: 10.1039/c5ee03874j. View

10.

Noel N, Abate A, Stranks S, Parrott E, Burlakov V, Goriely A . Enhanced photoluminescence and solar cell performance via Lewis base passivation of organic-inorganic lead halide perovskites. ACS Nano. 2014; 8(10):9815-21. DOI: 10.1021/nn5036476. View

11.

Lin K, Xing J, Quan L, Garcia de Arquer F, Gong X, Lu J . Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent. Nature. 2018; 562(7726):245-248. DOI: 10.1038/s41586-018-0575-3. View

12.

Zhang F, Shi W, Luo J, Pellet N, Yi C, Li X . Isomer-Pure Bis-PCBM-Assisted Crystal Engineering of Perovskite Solar Cells Showing Excellent Efficiency and Stability. Adv Mater. 2017; 29(17). DOI: 10.1002/adma.201606806. View

13.

Zhou Z, Wang Z, Zhou Y, Pang S, Wang D, Xu H . Methylamine-Gas-Induced Defect-Healing Behavior of CH3NH3PbI3 Thin Films for Perovskite Solar Cells. Angew Chem Int Ed Engl. 2015; 54(33):9705-9. DOI: 10.1002/anie.201504379. View

14.

Tan Z, Saberi Moghaddam R, Lai M, Docampo P, Higler R, Deschler F . Bright light-emitting diodes based on organometal halide perovskite. Nat Nanotechnol. 2014; 9(9):687-92. DOI: 10.1038/nnano.2014.149. View

15.

Deschler F, Price M, Pathak S, Klintberg L, Jarausch D, Higler R . High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors. J Phys Chem Lett. 2015; 5(8):1421-6. DOI: 10.1021/jz5005285. View

16.

Lee M, Teuscher J, Miyasaka T, Murakami T, Snaith H . Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science. 2012; 338(6107):643-7. DOI: 10.1126/science.1228604. View

17.

Tsai H, Nie W, Blancon J, Stoumpos C, Asadpour R, Harutyunyan B . High-efficiency two-dimensional Ruddlesden-Popper perovskite solar cells. Nature. 2016; 536(7616):312-6. DOI: 10.1038/nature18306. View

18.

McMeekin D, Wang Z, Rehman W, Pulvirenti F, Patel J, Noel N . Crystallization Kinetics and Morphology Control of Formamidinium-Cesium Mixed-Cation Lead Mixed-Halide Perovskite via Tunability of the Colloidal Precursor Solution. Adv Mater. 2017; 29(29). DOI: 10.1002/adma.201607039. View

19.

Milot R, Sutton R, Eperon G, Haghighirad A, Martinez Hardigree J, Miranda L . Charge-Carrier Dynamics in 2D Hybrid Metal-Halide Perovskites. Nano Lett. 2016; 16(11):7001-7007. DOI: 10.1021/acs.nanolett.6b03114. View

20.

Stranks S, Eperon G, Grancini G, Menelaou C, Alcocer M, Leijtens T . Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science. 2013; 342(6156):341-4. DOI: 10.1126/science.1243982. View