Flexible Solid-state Supercapacitor Based on Tin Oxide/reduced Graphene Oxide/bacterial Nanocellulose

Overview

Journal RSC Adv

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2022 May 13

PMID 35548204

Authors

Keng-Ku Liu

Qisheng Jiang

Clayton Kacica

Hamed Gholami Derami

Pratim Biswas

Srikanth Singamaneni

Affiliations

Soon will be listed here.

Abstract

We demonstrate a flexible and light-weight supercapacitor based on bacterial nanocellulose (BNC) incorporated with tin oxide (SnO) nanoparticles, graphene oxide (GO) and poly(3,4-ethylenedioxyiophene)-poly(styrenesulfonate) (PEDOT:PSS). The SnO and GO flakes are introduced into the fibrous nanocellulose matrix during bacteria-mediated synthesis. The flexible PEDOT:PSS/SnO/rGO/BNC electrodes exhibited excellent electrochemical performance with a capacitance of 445 F g at 2 A g and outstanding cycling stability with 84.1% capacitance retention over 2500 charge/discharge cycles. The flexible solid-state supercapacitors fabricated using PEDOT:PSS/SnO/rGO/BNC electrodes and poly(vinyl alcohol) (PVA)-HSO coated BNC as a separator exhibited excellent energy storage performance. The fabrication method demonstrated here is highly scalable and opens up new opportunities for the fabrication of flexible cellulose-based energy storage devices.

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References

Pham H, Pham V, Cuong T, Nguyen-Phan T, Chung J, Shin E . Synthesis of the chemically converted graphene xerogel with superior electrical conductivity. Chem Commun (Camb). 2011; 47(34):9672-4. DOI: 10.1039/c1cc13329b. View

Liu Z, Wu Z, Yang S, Dong R, Feng X, Mullen K . Ultraflexible In-Plane Micro-Supercapacitors by Direct Printing of Solution-Processable Electrochemically Exfoliated Graphene. Adv Mater. 2016; 28(11):2217-22. DOI: 10.1002/adma.201505304. View

Huang L, Chen D, Ding Y, Feng S, Wang Z, Liu M . Nickel-cobalt hydroxide nanosheets coated on NiCo2O4 nanowires grown on carbon fiber paper for high-performance pseudocapacitors. Nano Lett. 2013; 13(7):3135-9. DOI: 10.1021/nl401086t. View

Simon P, Gogotsi Y . Materials for electrochemical capacitors. Nat Mater. 2008; 7(11):845-54. DOI: 10.1038/nmat2297. View

Ko Y, Kwon M, Bae W, Lee B, Lee S, Cho J . Flexible supercapacitor electrodes based on real metal-like cellulose papers. Nat Commun. 2017; 8(1):536. PMC: 5599591. DOI: 10.1038/s41467-017-00550-3. View

Miller J, Simon P . Materials science. Electrochemical capacitors for energy management. Science. 2008; 321(5889):651-2. DOI: 10.1126/science.1158736. View

Gui Z, Zhu H, Gillette E, Han X, Rubloff G, Hu L . Natural cellulose fiber as substrate for supercapacitor. ACS Nano. 2013; 7(7):6037-46. DOI: 10.1021/nn401818t. View

Zhang C, Wu H, Yuan C, Guo Z, Lou X . Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries. Angew Chem Int Ed Engl. 2012; 51(38):9592-5. DOI: 10.1002/anie.201205292. View

Cao X, Shi Y, Shi W, Lu G, Huang X, Yan Q . Preparation of novel 3D graphene networks for supercapacitor applications. Small. 2011; 7(22):3163-8. DOI: 10.1002/smll.201100990. View

10.

Xu Y, Lin Z, Huang X, Wang Y, Huang Y, Duan X . Functionalized graphene hydrogel-based high-performance supercapacitors. Adv Mater. 2013; 25(40):5779-84. DOI: 10.1002/adma.201301928. View

11.

Zhang L, Zhao X . Carbon-based materials as supercapacitor electrodes. Chem Soc Rev. 2009; 38(9):2520-31. DOI: 10.1039/b813846j. View

12.

Yu G, Hu L, Liu N, Wang H, Vosgueritchian M, Yang Y . Enhancing the supercapacitor performance of graphene/MnO2 nanostructured electrodes by conductive wrapping. Nano Lett. 2011; 11(10):4438-42. DOI: 10.1021/nl2026635. View

13.

Yuan L, Xiao X, Ding T, Zhong J, Zhang X, Shen Y . Paper-based supercapacitors for self-powered nanosystems. Angew Chem Int Ed Engl. 2012; 51(20):4934-8. DOI: 10.1002/anie.201109142. View

14.

Liu W, Song M, Kong B, Cui Y . Flexible and Stretchable Energy Storage: Recent Advances and Future Perspectives. Adv Mater. 2017; 29(1). DOI: 10.1002/adma.201603436. View

15.

Wang H, Zhu B, Jiang W, Yang Y, Leow W, Wang H . A mechanically and electrically self-healing supercapacitor. Adv Mater. 2014; 26(22):3638-43. DOI: 10.1002/adma.201305682. View

16.

Marcano D, Kosynkin D, Berlin J, Sinitskii A, Sun Z, Slesarev A . Improved synthesis of graphene oxide. ACS Nano. 2010; 4(8):4806-14. DOI: 10.1021/nn1006368. View

17.

Hu L, Choi J, Yang Y, Jeong S, La Mantia F, Cui L . Highly conductive paper for energy-storage devices. Proc Natl Acad Sci U S A. 2009; 106(51):21490-4. PMC: 2799859. DOI: 10.1073/pnas.0908858106. View

18.

Liu L, Niu Z, Zhang L, Zhou W, Chen X, Xie S . Nanostructured graphene composite papers for highly flexible and foldable supercapacitors. Adv Mater. 2014; 26(28):4855-62. DOI: 10.1002/adma.201401513. View

19.

Tian R, Zhang Y, Chen Z, Duan H, Xu B, Guo Y . The effect of annealing on a 3D SnO2/graphene foam as an advanced lithium-ion battery anode. Sci Rep. 2016; 6:19195. PMC: 4709726. DOI: 10.1038/srep19195. View

20.

Wang G, Zhang L, Zhang J . A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev. 2011; 41(2):797-828. DOI: 10.1039/c1cs15060j. View