BiOBr Hybrids for Organic Pollutant Removal by the Combined Treatments of Adsorption and Photocatalysis

The SiO-BiOBr ( = 0-5) and SN-SiO-BiOBr hybrids were synthesized a facile one step co-precipitation method. To determine the optimal formula, the photocatalytic degradation of C. I. reactive red 2 (X3B) with SiO-BiOBr ( = 0-5) was investigated. Under simulated sunlight irradiation, 4SiO-BiOBr exhibited a better photocatalytic efficiency than other materials; 1.77 and 1.51 times higher than conventional nano TiO and pure BiOBr, respectively. To demonstrate the photocatalytic degradation mechanism, the effect of active species on degradation of X3B was carried out, and a possible degradation pathway was proposed. To realize the combined treatments of adsorption and photocatalysis, an inorganic/organic (I/O) SN-SiO-BiOBr hybrid was further strategized and synthesized. It showed much better adsorption performance than the SiO-BiOBr composite. It could enrich organic pollutants by facile adsorption, and then degrade them to HO and CO under natural sunlight irradiation. Notably, this sunlight-driven photocatalysis can be performed in the slurry resulted from the pollutant adsorption. As a result, the proposed combination of adsorption and photocatalysis will provide a novel strategy to greatly facilitate the treatment of organic wastewater.