Water and 2,2,6,6-tetra-methyl-piperidine: an Odd Couple Make a Solid Match
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Abstract
Commentary is given on a paper [Butler (2022). , , 364-369] reporting the crystallization of two room-temperature liquids, water and 2,2,6,6-tetra-methyl-piperidine, to form a crystalline solid with a water-lined channel potentially capable of proton transport.
References
1.
Butler I, Evans D, Horton P, Coles S, Parker S, Capelli S
. The spontaneous self-assembly of a molecular water pipe in 3D space. IUCrJ. 2022; 9(Pt 3):364-369.
PMC: 9067119.
DOI: 10.1107/S2052252522003396.
View
2.
Capelli S, Falvello L, Forcen-Vazquez E, McIntyre G, Palacio F, Sanz S
. Proton cascade in a molecular solid: H/D exchange on mobile and immobile water. Angew Chem Int Ed Engl. 2013; 52(50):13463-7.
DOI: 10.1002/anie.201307994.
View
3.
Cukierman S
. Et tu, Grotthuss! and other unfinished stories. Biochim Biophys Acta. 2006; 1757(8):876-85.
DOI: 10.1016/j.bbabio.2005.12.001.
View
4.
Nagle J, Morowitz H
. Molecular mechanisms for proton transport in membranes. Proc Natl Acad Sci U S A. 1978; 75(1):298-302.
PMC: 411234.
DOI: 10.1073/pnas.75.1.298.
View
5.
Adelroth P
. Special issue on proton transfer in biological systems. Biochim Biophys Acta. 2006; 1757(8):867-70.
DOI: 10.1016/j.bbabio.2006.08.011.
View