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Reduced Graphene Oxide-supported Ag-loaded Fe-doped TiO for the Degradation Mechanism of Methylene Blue and Its Electrochemical Properties

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Journal RSC Adv
Specialty Chemistry
Date 2022 May 11
PMID 35540418
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Abstract

Graphene oxide-based composites have been developed as cheap and effective photocatalysts for dye degradation and water splitting applications. Herein, we report reduced graphene oxide (rGO)/Ag/Fe-doped TiO that has been successfully prepared using a simple process. The resulting composites were characterized by a wide range of physicochemical techniques. The photocatalytic activities of the composite materials were studied under visible light supplied by a 35 W Xe arc lamp. The rGO/Ag/Fe-doped TiO composite demonstrated excellent degradation of methylene blue (MB) in 150 min and 4-nitrophenol (4-NP) in 210 min under visible light irradiation, and trapping experiments were carried out to explain the mechanism of photocatalytic activity. Moreover, electrochemical studies were carried out to demonstrate the oxygen evolution reaction (OER) activity on rGO/Ag/Fe-doped TiO in 1 M of HSO electrolyte, with a scan rate of 50 mV s. The reductions in overpotential are due to the d-orbital splitting in Fe-doped TiO and rGO as an electron collector and transporter.

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References
1.
Zhang H, Lv X, Li Y, Wang Y, Li J . P25-graphene composite as a high performance photocatalyst. ACS Nano. 2010; 4(1):380-6. DOI: 10.1021/nn901221k. View

2.
Balandin A, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F . Superior thermal conductivity of single-layer graphene. Nano Lett. 2008; 8(3):902-7. DOI: 10.1021/nl0731872. View

3.
Xiong Z, Zhang L, Ma J, Zhao X . Photocatalytic degradation of dyes over graphene-gold nanocomposites under visible light irradiation. Chem Commun (Camb). 2010; 46(33):6099-101. DOI: 10.1039/c0cc01259a. View

4.
Shan C, Yang H, Han D, Zhang Q, Ivaska A, Niu L . Water-soluble graphene covalently functionalized by biocompatible poly-L-lysine. Langmuir. 2009; 25(20):12030-3. DOI: 10.1021/la903265p. View

5.
Chen F, Yan F, Chen Q, Wang Y, Han L, Chen Z . Fabrication of Fe3O4@SiO2@TiO2 nanoparticles supported by graphene oxide sheets for the repeated adsorption and photocatalytic degradation of rhodamine B under UV irradiation. Dalton Trans. 2014; 43(36):13537-44. DOI: 10.1039/c4dt01702a. View