Facile Synthesis of Porous FeO@C Core/shell Nanorod/graphene for Improving Microwave Absorption Properties

Overview

Journal RSC Adv

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2022 May 11

PMID 35539449

Authors

Chen Fu

Dawei He

Yongsheng Wang

Xuan Zhao

Affiliations

Soon will be listed here.

Abstract

Porous FeO@C core/shell nanorods decorated with reduced graphene oxide (RGO) were fabricated through a facile one-pot method. The microwave absorption properties of the samples can be adjusted by the weight ratio of RGO. The addition of RGO not only effectively reduces the agglomeration of FeO@C, but also has a great effect on impedance matching and dielectric loss, resulting in enhanced microwave absorption abilities. The thickness corresponding to optimum reflection loss ( ) decreases as the weight ratio of RGO increases. For the FeO@C/RGO composite, a maximum value of -48.6 dB can be obtained at 13.9 GHz with a thickness of 3.0 mm, and the absorption bandwidth with below -10 dB is 7.1 GHz from 10.9 GHz to 18 GHz. These results demonstrate a facile method to prepare a highly efficient microwave absorption material with special microstructure.

Citing Articles

Effect of Ball Milling on the Absorption Properties of FeO.

Liang Y, Yuan Y, Huang Y, Wang Y, Wei S, Wang B Materials (Basel). 2020; 13(4).

PMID: 32079205 PMC: 7078717. DOI: 10.3390/ma13040883.

References

Wang G, Wu Y, Wei Y, Zhang X, Li Y, Li L . Fabrication of Reduced Graphene Oxide (RGO)/Co O Nanohybrid Particles and a RGO/Co O /Poly(vinylidene fluoride) Composite with Enhanced Wave-Absorption Properties. Chempluschem. 2020; 79(3):375-381. DOI: 10.1002/cplu.201300345. View

Ren Y, Zhu C, Zhang S, Li C, Chen Y, Gao P . Three-dimensional SiO2@Fe3O4 core/shell nanorod array/graphene architecture: synthesis and electromagnetic absorption properties. Nanoscale. 2013; 5(24):12296-303. DOI: 10.1039/c3nr04058e. View

Hu C, Mou Z, Lu G, Chen N, Dong Z, Hu M . 3D graphene-Fe3O4 nanocomposites with high-performance microwave absorption. Phys Chem Chem Phys. 2013; 15(31):13038-43. DOI: 10.1039/c3cp51253c. View

Wu T, Liu Y, Zeng X, Cui T, Zhao Y, Li Y . Facile Hydrothermal Synthesis of Fe3O4/C Core-Shell Nanorings for Efficient Low-Frequency Microwave Absorption. ACS Appl Mater Interfaces. 2016; 8(11):7370-80. DOI: 10.1021/acsami.6b00264. View

Liang B, Wang S, Kuang D, Hou L, Yu B, Lin L . Facile synthesis and excellent microwave absorption properties of FeCo-C core-shell nanoparticles. Nanotechnology. 2018; 29(8):085604. DOI: 10.1088/1361-6528/aaa52f. View

Wen B, Cao M, Lu M, Cao W, Shi H, Liu J . Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures. Adv Mater. 2014; 26(21):3484-9. DOI: 10.1002/adma.201400108. View

Singh K, Ohlan A, Pham V, R B, Varshney S, Jang J . Nanostructured graphene/Fe₃O₄ incorporated polyaniline as a high performance shield against electromagnetic pollution. Nanoscale. 2013; 5(6):2411-20. DOI: 10.1039/c3nr33962a. View

Qu B, Zhu C, Li C, Zhang X, Chen Y . Coupling Hollow Fe3O4-Fe Nanoparticles with Graphene Sheets for High-Performance Electromagnetic Wave Absorbing Material. ACS Appl Mater Interfaces. 2016; 8(6):3730-5. DOI: 10.1021/acsami.5b12789. View

Du Y, Liu W, Qiang R, Wang Y, Han X, Ma J . Shell thickness-dependent microwave absorption of core-shell Fe3O4@C composites. ACS Appl Mater Interfaces. 2014; 6(15):12997-3006. DOI: 10.1021/am502910d. View

10.

Liu Q, Cao Q, Bi H, Liang C, Yuan K, She W . CoNi@SiO2 @TiO2 and CoNi@Air@TiO2 Microspheres with Strong Wideband Microwave Absorption. Adv Mater. 2015; 28(3):486-90. DOI: 10.1002/adma.201503149. View

11.

Yan F, Guo D, Zhang S, Li C, Zhu C, Zhang X . An ultra-small NiFeO hollow particle/graphene hybrid: fabrication and electromagnetic wave absorption property. Nanoscale. 2018; 10(6):2697-2703. DOI: 10.1039/c7nr08305j. View

12.

Jian X, Wu B, Wei Y, Xue Dou S, Wang X, He W . Facile Synthesis of Fe3O4/GCs Composites and Their Enhanced Microwave Absorption Properties. ACS Appl Mater Interfaces. 2016; 8(9):6101-9. DOI: 10.1021/acsami.6b00388. View

13.

Zhao B, Fan B, Xu Y, Shao G, Wang X, Zhao W . Preparation of Honeycomb SnO₂ Foams and Configuration-Dependent Microwave Absorption Features. ACS Appl Mater Interfaces. 2015; 7(47):26217-25. DOI: 10.1021/acsami.5b08383. View

14.

Sun D, Zou Q, Wang Y, Wang Y, Jiang W, Li F . Controllable synthesis of porous Fe3O4@ZnO sphere decorated graphene for extraordinary electromagnetic wave absorption. Nanoscale. 2014; 6(12):6557-62. DOI: 10.1039/c3nr06797a. View