Functionalized Polycarbonates Triphenylborane Catalyzed Polymerization-hydrosilylation

Overview

Journal RSC Adv

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2022 May 9

PMID 35528568

Authors

Kori A Andrea

Francesca M Kerton

Affiliations

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Abstract

Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO to yield polycarbonates with excellent dispersity. assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37-110 °C were obtained.

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