Solid Oxide Fuel Cell with a Spin-coated Yttria Stabilized Zirconia/gadolinia Doped Ceria Bi-layer Electrolyte

A thin yttria stabilized zirconia (YSZ)/gadolinia doped ceria (GDC) bi-layer membrane is fabricated through the slurry spin coating technique and used as an electrolyte of a solid oxide fuel cell with LaSrCoFeO as the cathode. The viscosity of the YSZ slurry is controlled by adding ethanol in the terpineol solvent, which shows a negligible effect on the thickness but a remarkable influence on the porosity of the YSZ film. The thickness of the YSZ layer increases with the YSZ content in the slurry. The YSZ films are pre-sintered at various temperatures, and the one sintered at 1200 °C has a moderate interaction with the GDC slurry, forming a 10 μm-thick YSZ/GDC bilayer with a low porosity and a low ohmic resistance. The corresponding single cell shows a maximum power density of 1480 mW cm at 750 °C.