Mechanical and Self-recovery Properties of Supramolecular Ionic Liquid Elastomers Based on Host-guest Interactions and Correlation with Ionic Liquid Content

Overview

Journal RSC Adv

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2022 May 6

PMID 35519478

Authors

Garry Sinawang

Yuichiro Kobayashi

Motofumi Osaki

Yoshinori Takashima

Akira Harada

Hiroyasu Yamaguchi

Affiliations

Soon will be listed here.

Abstract

Supramolecular materials have received considerable attention due to their higher fracture energy and self-recovery capability compared to conventional chemically cross-linked materials. Herein, we focus on the mechanical properties and self-recovery behaviours of supramolecular polymeric elastomers swollen with ionic liquid. We also gained insight into the correlation between ionic liquid content and mechanical properties. These supramolecular polymers with ionic liquid can be easily prepared from bulk copolymerization of the host-guest complex (peracetylated cyclodextrin and adamantane derivatives) and alkyl acrylates and subsequent immersion in ionic liquid such as 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. The supramolecular polymeric elastomers showed a self-recovery ability, which the conventional chemically cross-linked elastomers with ionic liquid cannot achieve.

Citing Articles

Simultaneous control of the mechanical properties and adhesion of human umbilical vein endothelial cells to suppress platelet adhesion on a supramolecular substrate.

Park J, Ueda T, Kawai Y, Araki K, Kido M, Kure B RSC Adv. 2022; 12(43):27912-27917.

PMID: 36320244 PMC: 9523658. DOI: 10.1039/d2ra04885j.

References

Kato K, Okabe Y, Okazumi Y, Ito K . A significant impact of host-guest stoichiometry on the extensibility of polyrotaxane gels. Chem Commun (Camb). 2015; 51(90):16180-3. DOI: 10.1039/c5cc07122d. View

Xue M, Yang Y, Chi X, Zhang Z, Huang F . Pillararenes, a new class of macrocycles for supramolecular chemistry. Acc Chem Res. 2012; 45(8):1294-308. DOI: 10.1021/ar2003418. View

Armand M, Endres F, MacFarlane D, Ohno H, Scrosati B . Ionic-liquid materials for the electrochemical challenges of the future. Nat Mater. 2009; 8(8):621-9. DOI: 10.1038/nmat2448. View

Harrisson S, Mackenzie S, Haddleton D . Unprecedented solvent-induced acceleration of free-radical propagation of methyl methacrylate in ionic liquids. Chem Commun (Camb). 2002; (23):2850-1. DOI: 10.1039/b209479g. View

Wang Q, Mynar J, Yoshida M, Lee E, Lee M, Okuro K . High-water-content mouldable hydrogels by mixing clay and a dendritic molecular binder. Nature. 2010; 463(7279):339-43. DOI: 10.1038/nature08693. View

Chen S, Zhang N, Zhang B, Zhang B, Song J . Multifunctional Self-Healing Ionogels from Supramolecular Assembly: Smart Conductive and Remarkable Lubricating Materials. ACS Appl Mater Interfaces. 2018; 10(51):44706-44715. DOI: 10.1021/acsami.8b15722. View

Harner J, Hoagland D . Thermoreversible gelation of an ionic liquid by crystallization of a dissolved polymer. J Phys Chem B. 2010; 114(10):3411-8. DOI: 10.1021/jp9043144. View

Chen X, Dam M, Ono K, Mal A, Shen H, Nutt S . A thermally re-mendable cross-linked polymeric material. Science. 2002; 295(5560):1698-702. DOI: 10.1126/science.1065879. View

Cordier P, Tournilhac F, Soulie-Ziakovic C, Leibler L . Self-healing and thermoreversible rubber from supramolecular assembly. Nature. 2008; 451(7181):977-80. DOI: 10.1038/nature06669. View

10.

Ogoshi T, Yamagishi T, Nakamoto Y . Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry. Chem Rev. 2016; 116(14):7937-8002. DOI: 10.1021/acs.chemrev.5b00765. View

11.

Yan X, Wang F, Zheng B, Huang F . Stimuli-responsive supramolecular polymeric materials. Chem Soc Rev. 2012; 41(18):6042-65. DOI: 10.1039/c2cs35091b. View

12.

Roy N, Bruchmann B, Lehn J . DYNAMERS: dynamic polymers as self-healing materials. Chem Soc Rev. 2015; 44(11):3786-807. DOI: 10.1039/c5cs00194c. View

13.

Seki S, Susan M, Kaneko T, Tokuda H, Noda A, Watanabe M . Distinct difference in ionic transport behavior in polymer electrolytes depending on the matrix polymers and incorporated salts. J Phys Chem B. 2006; 109(9):3886-92. DOI: 10.1021/jp045328j. View

14.

Kaar J, Jesionowski A, Berberich J, Moulton R, Russell A . Impact of ionic liquid physical properties on lipase activity and stability. J Am Chem Soc. 2003; 125(14):4125-31. DOI: 10.1021/ja028557x. View

15.

Fox J, Wie J, Greenland B, Burattini S, Hayes W, Colquhoun H . High-strength, healable, supramolecular polymer nanocomposites. J Am Chem Soc. 2012; 134(11):5362-8. DOI: 10.1021/ja300050x. View

16.

Zhang W, Yuan C, Guo J, Qiu L, Yan F . Supramolecular ionic liquid gels for quasi-solid-state dye-sensitized solar cells. ACS Appl Mater Interfaces. 2014; 6(11):8723-8. DOI: 10.1021/am501523x. View

17.

Susan M, Kaneko T, Noda A, Watanabe M . Ion gels prepared by in situ radical polymerization of vinyl monomers in an ionic liquid and their characterization as polymer electrolytes. J Am Chem Soc. 2005; 127(13):4976-83. DOI: 10.1021/ja045155b. View

18.

Wojtecki R, Meador M, Rowan S . Using the dynamic bond to access macroscopically responsive structurally dynamic polymers. Nat Mater. 2010; 10(1):14-27. DOI: 10.1038/nmat2891. View

19.

Harada A, Takashima Y, Nakahata M . Supramolecular polymeric materials via cyclodextrin-guest interactions. Acc Chem Res. 2014; 47(7):2128-40. DOI: 10.1021/ar500109h. View

20.

Nakahata M, Takashima Y, Harada A . Highly Flexible, Tough, and Self-Healing Supramolecular Polymeric Materials Using Host-Guest Interaction. Macromol Rapid Commun. 2015; 37(1):86-92. DOI: 10.1002/marc.201500473. View