» Articles » PMID: 35480834

Recent Advances in the Metal-organic Framework-based Electrocatalysts for the Hydrogen Evolution Reaction in Water Splitting: a Review

Overview
Journal RSC Adv
Specialty Chemistry
Date 2022 Apr 28
PMID 35480834
Authors
Affiliations
Soon will be listed here.
Abstract

Water splitting is an important technology for alternative and sustainable energy storage, and a way for the production of hydrogen without generating pollution. In recent years, metal-organic frameworks (MOFs) have become the most capable multifunctional resources because of their high surface areas, tunable porosity, simple modification of compositions, and potential for use as precursors with a variety of morphological structures. Based on these qualities, many MOFs and their derived materials are utilized as electrocatalysts for the water splitting reaction. Herein, we assembled the relevant literature in recent years about MOF and MOF-derived materials for their eminent electrocatalytic activity in water splitting with useful strategies for the design and preparation of catalysts, along with challenges. This review summarizes the advancement in MOF materials, elucidating different strategies for its role in water splitting.

Citing Articles

Advances in Catalysts for Hydrogen Production: A Comprehensive Review of Materials and Mechanisms.

Kumar N, Aepuru R, Lee S, Park S Nanomaterials (Basel). 2025; 15(4).

PMID: 39997819 PMC: 11858572. DOI: 10.3390/nano15040256.


Fabrication of MoS/rGO hybrids as electrocatalyst for water splitting applications.

Khan M, Noor T, Pervaiz E, Iqbal N, Zaman N RSC Adv. 2024; 14(18):12742-12753.

PMID: 38645523 PMC: 11027038. DOI: 10.1039/d4ra00697f.


A zeolitic imidazolate framework (ZIF-67) and graphitic carbon nitride (g-CN) composite based efficient electrocatalyst for overall water-splitting reaction.

Khan S, Noor T, Iqbal N, Pervaiz E, Yaqoob L RSC Adv. 2023; 13(36):24973-24987.

PMID: 37614795 PMC: 10442768. DOI: 10.1039/d3ra04783k.


A DFT Study of Ruthenium Nano-Dots: Size-Dependent Induced Magnetic Moments.

Ungerer M, de Leeuw N Nanomaterials (Basel). 2023; 13(6).

PMID: 36986012 PMC: 10058763. DOI: 10.3390/nano13061118.


A comprehensive review on the electrochemical parameters and recent material development of electrochemical water splitting electrocatalysts.

Raveendran A, Chandran M, Dhanusuraman R RSC Adv. 2023; 13(6):3843-3876.

PMID: 36756592 PMC: 9890951. DOI: 10.1039/d2ra07642j.


References
1.
Micheroni D, Lan G, Lin W . Efficient Electrocatalytic Proton Reduction with Carbon Nanotube-Supported Metal-Organic Frameworks. J Am Chem Soc. 2018; 140(46):15591-15595. DOI: 10.1021/jacs.8b09521. View

2.
Zhang Z, Zhang S, Yao Q, Chen X, Lu Z . Controlled Synthesis of MOF-Encapsulated NiPt Nanoparticles toward Efficient and Complete Hydrogen Evolution from Hydrazine Borane and Hydrazine. Inorg Chem. 2017; 56(19):11938-11945. DOI: 10.1021/acs.inorgchem.7b01910. View

3.
Liu P, Gu X, Kang K, Zhang H, Cheng J, Su H . Highly Efficient Catalytic Hydrogen Evolution from Ammonia Borane Using the Synergistic Effect of Crystallinity and Size of Noble-Metal-Free Nanoparticles Supported by Porous Metal-Organic Frameworks. ACS Appl Mater Interfaces. 2017; 9(12):10759-10767. DOI: 10.1021/acsami.7b01161. View

4.
Zhang H, An P, Zhou W, Guan B, Zhang P, Dong J . Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction. Sci Adv. 2018; 4(1):eaao6657. PMC: 5775028. DOI: 10.1126/sciadv.aao6657. View

5.
Aneeshkumar K, Tseng J, Liu X, Tian J, Diao D, Shen J . Electrochemically dealloyed nanoporous FeNiCoPC metallic glass for efficient and stable electrocatalytic hydrogen and oxygen generation. RSC Adv. 2022; 11(13):7369-7380. PMC: 8694965. DOI: 10.1039/d0ra10418c. View