Experimental and Theoretical Study on the Corrosion Inhibition of Mild Steel by Nonanedioic Acid Derivative in Hydrochloric Acid Solution

Overview

Journal Sci Rep

Specialty Science

Date 2022 Mar 19

PMID 35304485

Authors

Ahmed A Al-Amiery

Abu Bakar Mohamad

Abdul Amir H Kadhum

Lina M Shaker

Wan Nor Roslam Wan Isahak

Mohd S Takriff

Affiliations

Soon will be listed here.

Abstract

The corrosion performance of mild steel (MS) in 1M HCl solution was examined by weight loss (WL), potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), electrochemical frequency modulation (EFM), and open circuit potential (OCP) measurements in the absence and presence of nonanedihydrazide. PDP measurements indicated that nonanedihydrazide acts as a mixed inhibitor due to its adsorption on the MS surface, exhibiting an inhibition efficiency of more than 97%. The surface morphology investigation of the protective layer on the MS surface confirmed that adsorption of nonanedihydrazide molecules occurred via chemical adsorption following Langmuir's isotherm model. The effect of temperature on the corrosion performance in the presence of nonanedihydrazide was investigated in the range of 303-333 K, showing that the inhibition efficiency increased with an increase in the inhibitor concentration and decreased with an increase in temperature. A new green corrosion inhibitor was synthesised and theoretical computations were conducted to completely understand the inhibition mechanism. Nonanedihydrazide molecules were investigated by DFT (density functional theory) using the B3LYP functional to evaluate the relationship of corrosion inhibition performance and the molecular structure. The computed theoretical parameters presented significant support for understanding the inhibitive mechanism revealed by the inhibitory molecules and are in good agreement with WL, PDP, EIS, (EFM), and OCP results.

Citing Articles

Sustainable corrosion prevention of mild steel in acidic media with herb extract.

Kumari A, Kaur N, Kaur M, Husain F, Bhowmik P, Sohal H RSC Adv. 2025; 15(2):924-937.

PMID: 39807195 PMC: 11726314. DOI: 10.1039/d4ra07958b.

Electrochemical and quantum chemical investigation on the adsorption behavior of a schiff base and its metal complex for corrosion protection of mild steel in 15 wt% HCl solution.

El-Haitout B, Sardjono R, Es-Sounni B, Chafiq M, Salghi R, Bakhouch M Heliyon. 2024; 10(23):e40662.

PMID: 39660179 PMC: 11629228. DOI: 10.1016/j.heliyon.2024.e40662.

Synthesis of a new quaternary ammonium salt for efficient inhibition of mild steel corrosion in 15 % HCl: Experimental and theoretical studies.

Goni L, Ali S, Al-Muallem H, Jafar Mazumder M Heliyon. 2024; 10(19):e38425.

PMID: 39416823 PMC: 11482660. DOI: 10.1016/j.heliyon.2024.e38425.

Synergistic inhibition effect of diolefinic dye and silver nanoparticles for carbon steel corrosion in hydrochloric acid solution.

El-Nahass M, Fayed T, El-Gamil M, Fouda A BMC Chem. 2024; 18(1):193.

PMID: 39369236 PMC: 11456253. DOI: 10.1186/s13065-024-01298-w.

Insights into the newly synthesized bi- Mannich base for carbon steel corrosion inhibition in HS and HCl solution.

Shen C, Yan J, Ai Z, Huang H, Mo L, Liang B Sci Rep. 2024; 14(1):19869.

PMID: 39191811 PMC: 11349759. DOI: 10.1038/s41598-024-70905-6.

References

Singh Chauhan D, Quraishi M, Sorour A, Saha S, Banerjee P . Triazole-modified chitosan: a biomacromolecule as a new environmentally benign corrosion inhibitor for carbon steel in a hydrochloric acid solution. RSC Adv. 2022; 9(26):14990-15003. PMC: 9064206. DOI: 10.1039/c9ra00986h. View

Haque J, Srivastava V, Chauhan D, Lgaz H, Quraishi M . Microwave-Induced Synthesis of Chitosan Schiff Bases and Their Application as Novel and Green Corrosion Inhibitors: Experimental and Theoretical Approach. ACS Omega. 2019; 3(5):5654-5668. PMC: 6641920. DOI: 10.1021/acsomega.8b00455. View

Oguzie E, Enenebeaku C, Akalezi C, Okoro S, Ayuk A, Ejike E . Adsorption and corrosion-inhibiting effect of Dacryodis edulis extract on low-carbon-steel corrosion in acidic media. J Colloid Interface Sci. 2010; 349(1):283-92. DOI: 10.1016/j.jcis.2010.05.027. View

Sukul D, Pal A, Saha S, Satpati S, Adhikari U, Banerjee P . Newly synthesized quercetin derivatives as corrosion inhibitors for mild steel in 1 M HCl: combined experimental and theoretical investigation. Phys Chem Chem Phys. 2018; 20(9):6562-6574. DOI: 10.1039/c7cp06848d. View

H Kadhum A, Mohamad A, Hammed L, A Al-Amiery A, San N, Musa A . Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by New Coumarin. Materials (Basel). 2017; 7(6):4335-4348. PMC: 5455929. DOI: 10.3390/ma7064335. View

A Al-Amiery A, H Kadhum A, Mohamad A, Junaedi S . A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl. Materials (Basel). 2017; 6(4):1420-1431. PMC: 5452315. DOI: 10.3390/ma6041420. View

Uwaya G, Fayemi O, Sherif E, Junaedi H, Ebenso E . Synthesis, Electrochemical Studies, and Antimicrobial Properties of FeO Nanoparticles from Plant Extracts. Materials (Basel). 2020; 13(21). PMC: 7663161. DOI: 10.3390/ma13214894. View

Nahle A, Salim R, El Hajjaji F, Aouad M, Messali M, Ech-Chihbi E . Novel triazole derivatives as ecological corrosion inhibitors for mild steel in 1.0 M HCl: experimental & theoretical approach. RSC Adv. 2022; 11(7):4147-4162. PMC: 8694344. DOI: 10.1039/d0ra09679b. View

Espinoza-Vazquez A, Rodriguez-Gomez F, Martinez-Cruz I, Angeles-Beltran D, Negron-Silva G, Palomar-Pardave M . Adsorption and corrosion inhibition behaviour of new theophylline-triazole-based derivatives for steel in acidic medium. R Soc Open Sci. 2019; 6(3):181738. PMC: 6458416. DOI: 10.1098/rsos.181738. View

10.

Plakhutin B, Davidson E . Koopmans' theorem in the restricted open-shell Hartree-Fock method. 1. A variational approach. J Phys Chem A. 2009; 113(45):12386-95. DOI: 10.1021/jp9002593. View

11.

Qiang Y, Guo L, Zhang S, Li W, Yu S, Tan J . Synergistic effect of tartaric acid with 2,6-diaminopyridine on the corrosion inhibition of mild steel in 0.5 M HCl. Sci Rep. 2016; 6:33305. PMC: 5024118. DOI: 10.1038/srep33305. View

12.

El-Etre A . Inhibition of acid corrosion of carbon steel using aqueous extract of olive leaves. J Colloid Interface Sci. 2007; 314(2):578-83. DOI: 10.1016/j.jcis.2007.05.077. View

13.

DODSON R, King L . The reaction of ketones with halogens and thiourea. J Am Chem Soc. 2010; 67:2242. DOI: 10.1021/ja01228a059. View

14.

A Al-Amiery A, H Kadhum A, Mohamad A, Musa A, Li C . Electrochemical Study on Newly Synthesized Chlorocurcumin as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid. Materials (Basel). 2017; 6(12):5466-5477. PMC: 5452761. DOI: 10.3390/ma6125466. View

15.

Junaedi S, A Al-Amiery A, Kadihum A, H Kadhum A, Mohamad A . Inhibition effects of a synthesized novel 4-aminoantipyrine derivative on the corrosion of mild steel in hydrochloric acid solution together with quantum chemical studies. Int J Mol Sci. 2013; 14(6):11915-28. PMC: 3709763. DOI: 10.3390/ijms140611915. View

16.

Singh Chauhan D, Mazumder M, Quraishi M, Ansari K, Suleiman R . Microwave-assisted synthesis of a new Piperonal-Chitosan Schiff base as a bio-inspired corrosion inhibitor for oil-well acidizing. Int J Biol Macromol. 2020; 158:231-243. DOI: 10.1016/j.ijbiomac.2020.04.195. View

17.

Wei Z, Duby P, Somasundaran P . Pitting inhibition of stainless steel by surfactants: an electrochemical and surface chemical approach. J Colloid Interface Sci. 2003; 259(1):97-102. DOI: 10.1016/s0021-9797(03)00025-0. View

18.

Yang W, Mortier W . The use of global and local molecular parameters for the analysis of the gas-phase basicity of amines. J Am Chem Soc. 2011; 108(19):5708-11. DOI: 10.1021/ja00279a008. View