Selective Photocatalytic CO Reduction in Aerobic Environment by Microporous Pd-porphyrin-based Polymers Coated Hollow TiO

Overview

Journal Nat Commun

Specialty Biology

Date 2022 Mar 18

PMID 35301319

Authors

Yajuan Ma

Xiaoxuan Yi

Shaolei Wang

Tao Li

Bien Tan

Chuncheng Chen

Tetsuro Majima

Eric R Waclawik

Huaiyong Zhu

Jingyu Wang

Affiliations

Soon will be listed here.

Abstract

Direct photocatalytic CO reduction from primary sources, such as flue gas and air, into fuels, is highly desired, but the thermodynamically favored O reduction almost completely impedes this process. Herein, we report on the efficacy of a composite photocatalyst prepared by hyper-crosslinking porphyrin-based polymers on hollow TiO surface and subsequent coordinating with Pd(II). Such composite exhibits high resistance against O inhibition, leading to 12% conversion yield of CO from air after 2-h UV-visible light irradiation. In contrast, the CO reduction over Pd/TiO without the polymer is severely inhibited by the presence of O ( ≥ 0.2 %). This study presents a feasible strategy, building Pd(II) sites into CO-adsorptive polymers on hollow TiO surface, for realizing CO reduction with HO in an aerobic environment by the high CO/O adsorption selectivity of polymers and efficient charge separation for CO reduction and HO oxidation on Pd(II) sites and hollow TiO, respectively.

Citing Articles

Floatable artificial leaf to couple oxygen-tolerant CO conversion with water purification.

Zhang Z, Wang Y, Xie Y, Tsukamoto T, Zhao Q, Huang Q Nat Commun. 2025; 16(1):274.

PMID: 39747259 PMC: 11696042. DOI: 10.1038/s41467-024-55753-2.

Synergistic metal halide perovskite@metal-organic framework hybrids for photocatalytic CO reduction.

Sharma S, Jacob N, Grandhi G, Choudhary M, Ippili S, Hathwar V iScience. 2024; 27(10):110924.

PMID: 39346676 PMC: 11439556. DOI: 10.1016/j.isci.2024.110924.

A robust Fe-based heterogeneous photocatalyst for the visible-light-mediated selective reduction of an impure CO stream.

Ghosh T, Ren P, Franck P, Tang M, Jaworski A, Barcaro G Chem Sci. 2024; 15(29):11488-11499.

PMID: 39055026 PMC: 11268485. DOI: 10.1039/d4sc02773f.

Contact-electro-catalytic CO reduction from ambient air.

Wang N, Jiang W, Yang J, Feng H, Zheng Y, Wang S Nat Commun. 2024; 15(1):5913.

PMID: 39003260 PMC: 11246423. DOI: 10.1038/s41467-024-50118-1.

Hydrogen Production via Electrolysis of Wastewater.

Huang L, Fang C, Pan T, Zhu Q, Geng T, Li G Nanomaterials (Basel). 2024; 14(7).

PMID: 38607103 PMC: 11013150. DOI: 10.3390/nano14070567.

References

Yan H, Cheng H, Yi H, Lin Y, Yao T, Wang C . Single-Atom Pd₁/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene. J Am Chem Soc. 2015; 137(33):10484-7. DOI: 10.1021/jacs.5b06485. View

Zhang H, Wang Y, Zuo S, Zhou W, Zhang J, Lou X . Isolated Cobalt Centers on WO Nanowires Perform as a Reaction Switch for Efficient CO Photoreduction. J Am Chem Soc. 2021; 143(5):2173-2177. DOI: 10.1021/jacs.0c08409. View

Long R, Li Y, Liu Y, Chen S, Zheng X, Gao C . Isolation of Cu Atoms in Pd Lattice: Forming Highly Selective Sites for Photocatalytic Conversion of CO to CH. J Am Chem Soc. 2017; 139(12):4486-4492. DOI: 10.1021/jacs.7b00452. View

Han B, Ou X, Deng Z, Song Y, Tian C, Deng H . Nickel Metal-Organic Framework Monolayers for Photoreduction of Diluted CO : Metal-Node-Dependent Activity and Selectivity. Angew Chem Int Ed Engl. 2018; 57(51):16811-16815. DOI: 10.1002/anie.201811545. View

Son S, Hwang S, Kim C, Yun J, Jang J . Designed synthesis of SiO2/TiO2 core/shell structure as light scattering material for highly efficient dye-sensitized solar cells. ACS Appl Mater Interfaces. 2013; 5(11):4815-20. DOI: 10.1021/am400441v. View

Lu X, Jiang Z, Yuan X, Wu Y, Malpass-Evans R, Zhong Y . A bio-inspired O-tolerant catalytic CO reduction electrode. Sci Bull (Beijing). 2023; 64(24):1890-1895. DOI: 10.1016/j.scib.2019.04.008. View

Neatu S, Macia-Agullo J, Concepcion P, Garcia H . Gold-copper nanoalloys supported on TiO2 as photocatalysts for CO2 reduction by water. J Am Chem Soc. 2014; 136(45):15969-76. DOI: 10.1021/ja506433k. View

Wu X, Li Y, Zhang G, Chen H, Li J, Wang K . Photocatalytic CO Conversion of MWO Directly from the Air with High Selectivity: Insight into Full Spectrum-Induced Reaction Mechanism. J Am Chem Soc. 2019; 141(13):5267-5274. DOI: 10.1021/jacs.8b12928. View

Zhou S, Shang L, Zhao Y, Shi R, Waterhouse G, Huang Y . Pd Single-Atom Catalysts on Nitrogen-Doped Graphene for the Highly Selective Photothermal Hydrogenation of Acetylene to Ethylene. Adv Mater. 2019; 31(18):e1900509. DOI: 10.1002/adma.201900509. View

10.

Li X, Yu J, Jaroniec M, Chen X . Cocatalysts for Selective Photoreduction of CO into Solar Fuels. Chem Rev. 2019; 119(6):3962-4179. DOI: 10.1021/acs.chemrev.8b00400. View

11.

Schukraft G, Woodward R, Kumar S, Sachs M, Eslava S, Petit C . Hypercrosslinked Polymers as a Photocatalytic Platform for Visible-Light-Driven CO Photoreduction Using H O. ChemSusChem. 2021; 14(7):1720-1727. PMC: 8048809. DOI: 10.1002/cssc.202002824. View

12.

Sheng J, He Y, Li J, Yuan C, Huang H, Wang S . Identification of Halogen-Associated Active Sites on Bismuth-Based Perovskite Quantum Dots for Efficient and Selective CO-to-CO Photoreduction. ACS Nano. 2020; 14(10):13103-13114. DOI: 10.1021/acsnano.0c04659. View

13.

Dilla M, Jakubowski A, Ristig S, Strunk J, Schlogl R . The fate of O in photocatalytic CO reduction on TiO under conditions of highest purity. Phys Chem Chem Phys. 2019; 21(29):15949-15957. DOI: 10.1039/c8cp07765g. View

14.

Das S, Bhanja P, Kundu S, Mondal S, Bhaumik A . Role of Surface Phenolic-OH Groups in N-Rich Porous Organic Polymers for Enhancing the CO Uptake and CO/N Selectivity: Experimental and Computational Studies. ACS Appl Mater Interfaces. 2018; 10(28):23813-23824. DOI: 10.1021/acsami.8b05849. View

15.

Wang G, He C, Huang R, Mao J, Wang D, Li Y . Photoinduction of Cu Single Atoms Decorated on UiO-66-NH for Enhanced Photocatalytic Reduction of CO to Liquid Fuels. J Am Chem Soc. 2020; 142(45):19339-19345. DOI: 10.1021/jacs.0c09599. View

16.

Lan Z, Zhang G, Chen X, Zhang Y, Zhang K, Wang X . Reducing the Exciton Binding Energy of Donor-Acceptor-Based Conjugated Polymers to Promote Charge-Induced Reactions. Angew Chem Int Ed Engl. 2019; 58(30):10236-10240. DOI: 10.1002/anie.201904904. View

17.

Wang S, Zhang C, Shu Y, Jiang S, Xia Q, Chen L . Layered microporous polymers by solvent knitting method. Sci Adv. 2017; 3(3):e1602610. PMC: 5376128. DOI: 10.1126/sciadv.1602610. View

18.

Wang S, Xu M, Peng T, Zhang C, Li T, Hussain I . Porous hypercrosslinked polymer-TiO-graphene composite photocatalysts for visible-light-driven CO conversion. Nat Commun. 2019; 10(1):676. PMC: 6368626. DOI: 10.1038/s41467-019-08651-x. View

19.

Saito D, Yamazaki Y, Tamaki Y, Ishitani O . Photocatalysis of a Dinuclear Ru(II)-Re(I) Complex for CO Reduction on a Solid Surface. J Am Chem Soc. 2020; 142(45):19249-19258. DOI: 10.1021/jacs.0c09170. View

20.

Kajiwara T, Fujii M, Tsujimoto M, Kobayashi K, Higuchi M, Tanaka K . Photochemical Reduction of Low Concentrations of CO2 in a Porous Coordination Polymer with a Ruthenium(II)-CO Complex. Angew Chem Int Ed Engl. 2016; 55(8):2697-700. DOI: 10.1002/anie.201508941. View