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Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath

Overview
Journal Entropy (Basel)
Publisher MDPI
Date 2022 Feb 25
PMID 35205484
Authors
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Abstract

The standard textbooks contain good explanations of how and why equilibrium thermodynamics emerges in a reservoir with particles that are subjected to Gaussian noise. However, in systems that convert or transport energy, the noise is often not Gaussian. Instead, displacements exhibit an α-stable distribution. Such noise is commonly called Lévy noise. With such noise, we see a thermodynamics that deviates from what traditional equilibrium theory stipulates. In addition, with particles that can propel themselves, so-called active particles, we find that the rules of equilibrium thermodynamics no longer apply. No general nonequilibrium thermodynamic theory is available and understanding is often ad hoc. We study a system with overdamped particles that are subjected to Lévy noise. We pick a system with a geometry that leads to concise formulae to describe the accumulation of particles in a cavity. The nonhomogeneous distribution of particles can be seen as a dissipative structure, i.e., a lower-entropy steady state that allows for throughput of energy and concurrent production of entropy. After the mechanism that maintains nonequilibrium is switched off, the relaxation back to homogeneity represents an increase in entropy and a decrease of free energy. For our setup we can analytically connect the nonequilibrium noise and active particle behavior to entropy decrease and energy buildup with simple and intuitive formulae.

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References
1.
Spiechowicz J, Luczka J . Arcsine law and multistable Brownian dynamics in a tilted periodic potential. Phys Rev E. 2021; 104(2-1):024132. DOI: 10.1103/PhysRevE.104.024132. View

2.
Wang G, Sevick E, Mittag E, Searles D, Evans D . Experimental demonstration of violations of the second law of thermodynamics for small systems and short time scales. Phys Rev Lett. 2002; 89(5):050601. DOI: 10.1103/PhysRevLett.89.050601. View

3.
Evans , Searles . Equilibrium microstates which generate second law violating steady states. Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics. 1994; 50(2):1645-1648. DOI: 10.1103/physreve.50.1645. View

4.
Penna , de Oliveira PM , Sartorelli , Goncalves , Pinto . Long-range anticorrelations and non-Gaussian behavior of a leaky faucet. Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics. 1995; 52(3):R2168-R2171. DOI: 10.1103/physreve.52.r2168. View

5.
Zweiback , Cowan , Smith , Hartley , Howell , Steinke . Characterization of fusion burn time in exploding deuterium cluster plasmas. Phys Rev Lett. 2000; 85(17):3640-3. DOI: 10.1103/PhysRevLett.85.3640. View