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MXene/AgCrO Nanocomposite As Supercapacitors Electrode

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Publisher MDPI
Date 2021 Oct 23
PMID 34683600
Citations 4
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Abstract

MXene/AgCrO nanocomposite was synthesized effectively by means of superficial low-cost co-precipitation technique in order to inspect its capacitive storage potential for supercapacitors. MXene was etched from MAX powder and AgCrO spinel was synthesized by an easy sol-gel scheme. X-Ray diffraction (XRD) revealed an addition in inter-planar spacing from 4.7 Å to 6.2 Å while AgCrO nanoparticles diffused in form of clusters over MXene layers that had been explored by scanning electron microscopy (SEM). Energy dispersive X-Ray (EDX) demonstrated the elemental analysis. Raman spectroscopy opens the gap between bonding structure of as-synthesized nanocomposite. From photoluminence (PL) spectra the energy band gap value 3.86 eV was estimated. Electrode properties were characterized by applying electrochemical observations such as cyclic voltammetry along with electrochemical impedance spectroscopy (EIS) for understanding redox mechanism and electron transfer rate constant K. Additionally, this novel work will be an assessment to analyze the capacitive behavior of electrode in different electrolytes such as in acidic of 0.1 M HSO has specific capacitance C = 525 F/g at 10 mVs and much low value in basic of 1 M KOH electrolyte. This paper reflects the novel synthesis and applications of MXene/AgCrO nanocomposite electrode fabrication in energy storage devices such as supercapacitors.

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