Visible-light-driven Z-scheme Protonated G-CN/wood Flour Biochar/BiVO Photocatalyst with Biochar As Charge-transfer Channel for Enhanced RhB Degradation and Cr(VI) Reduction

For the simultaneous photocatalytic reduction of hexavalent chromium (Cr(VI)) and the degradation of rhodamine B (RhB), directional charge-transfer channels and efficient separation of photogenerated holes and electrons are important. Herein, a Z-scheme heterojunction photocatalyst, protonated g-CN/BiVO decorated with wood flour biochar (pCN/WFB/BiVO), was prepared through a hydrothermal reaction and electrostatic self-assembly for Cr(VI) photoreduction and RhB photodegradation. The morphological features, crystalline structure, chemical composition, optical properties, specific surface area, and photoelectrochemical properties of the prepared samples were investigated. The pCN/WFB/BiVO photocatalyst exhibited superior removal performance when used to remove Cr(VI) and RhB separately or RhB-Cr(VI) system. The biochar bridge served as a charge-transfer channel between two semiconductors, and the electrons in protonated g-CN (pCN) and BiVO achieved a charge balance. This led to the formation of a Z-scheme heterojunction, fast photogenerated charge separation, and a powerful redox ability. The pCN/WFB/BiVO photocatalyst provides new insight into the mechanisms responsible for boosting multicomponent photocatalytic reactions, while constituting a promising candidate for wastewater treatment.