Binding a Meridional Ligand in a Facial Geometry: A Square Peg in a Round Hole

Overview

Journal J Organomet Chem

Specialty Chemistry

Date 2021 Aug 9

PMID 34366484

Citations 1

Authors

Briana R Schrage

Dominick Vitale

Kimberly A Kelly

Victor N Nemykin

Richard S Herrick

Christopher J Ziegler

Affiliations

Soon will be listed here.

Abstract

The bis(pyridylimino)isoindoline (BPI) ligand is a tridentate chelate that binds to metals via a meridional coordination mode. However, when this ligand forms a complex with Re(CO), an almost exclusively facial moiety, the BPI ligand deforms to coordinate in a facial mode. We have in-vestigated this deformation via structural and theoretical means, and the non-planar binding mode of the ligand bathochromically shifts the metal to ligand charge transfer (MLCT) transition.

Citing Articles

Luminescent Pt(II) Complexes Using Unsymmetrical Bis(2-pyridylimino)isoindolate Analogues.

Payce E, Knighton R, Platts J, Horton P, Coles S, Pope S Inorg Chem. 2024; 63(18):8273-8285.

PMID: 38656154 PMC: 11080048. DOI: 10.1021/acs.inorgchem.4c00558.

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