Adsorptive Removal of Dyes from Wastewater Using a Metal-organic Framework: A Review

Water pollution from synthetic dyes is a growing environmental concern because many dyes have carcinogenic effects on humans and aquatic life. Adsorption is a widely used technology for the separation and removal of dyes from wastewater. However, the dye removal process using conventional adsorbents is not sufficiently efficient for industrial wastewater. Metal-organic frameworks (MOFs) addresses these drawbacks. MOF showed excellent dye removal and degradation capacity owing to its multifunctionality, water-stability, large surface area, tunable pore size and recyclability. Magnetic MOFs retained excellent performance up to several consecutive cycles. Modified MOFs performed as Fenton-like catalysis process which generated abundant reactive radicals that degraded complex organic dyes into simple and less toxic forms which were further adsorbed onto the MOF. This review systematically compiles in-depth studies on the adsorptive removal of dyes from wastewater, MOF adsorption mechanisms, major influencing factors, to adsorption efficiency of MOFs. While all MOFs adsorb dyes through electrostatic attraction, the type of MOF, presence of functional groups, ligands, and pH significantly control the adsorption mechanism. Before developing an MOF, optimization and upgradation of factors and interaction between available adsorption site and adsorbate is needed. Finally, the prospects and new frontiers of MOFs in sustainable water treatment is discussed.