Stereospecific Synthesis of Chiral P-containing Polyaromatics Based on 7-membered P-rings

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2021 Jul 1

PMID 34195719

Citations 4

Authors

Reka Mokrai

Anabella Mocanu

Matthew P Duffy

Thomas Vives

Elsa Caytan

Vincent Dorcet

Thierry Roisnel

Laszlo Nyulaszi

Zoltan Benko

Pierre-Antoine Bouit

Muriel Hissler

Affiliations

Soon will be listed here.

Abstract

We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.

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