An Advancement in the Synthesis of Nano Pd@magnetic Amine-Functionalized UiO-66-NH Catalyst for Cyanation and O-arylation Reactions

Overview

Journal Sci Rep

Specialty Science

Date 2021 Jun 1

PMID 34059726

Citations 4

Authors

Firouz Matloubi Moghaddam

Atefeh Jarahiyan

Mahdi Heidarian Haris

Ali Pourjavadi

Affiliations

Soon will be listed here.

Abstract

The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of benzonitriles and diarylethers of aryl halides under optimal conditions. The MOF catalyst was built based on magnetic nanoparticles and UiO-66-NH which further modified with 2,4,6-trichloro-1,3,5-triazine and 5-phenyl tetrazole at the same time and the catalyst structure was confirmed by various techniques. This new modification has been applied to increase anchoring palladium into the support. Furthermore, the products' yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing palladium. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs.

Citing Articles

URJC-1: Stable and Efficient Catalyst for O-Arylation Cross-Coupling.

Garcia-Rojas E, Leo P, Tapiador J, Martos C, Orcajo G Nanomaterials (Basel). 2024; 14(13).

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Ti-based MOFs with acetic acid pendings as an efficient catalyst in the preparation of new spiropyrans with biological moieties.

Torkashvand Z, Sepehrmansourie H, Zolfigol M, Gu Y Sci Rep. 2024; 14(1):14101.

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Application of Zr-MOFs based copper complex in synthesis of pyrazolo[3, 4-b]pyridine-5-carbonitriles via anomeric-based oxidation.

Tavakoli E, Sepehrmansourie H, Zarei M, Zolfigol M, Khazaei A, AsHabi M Sci Rep. 2023; 13(1):9388.

PMID: 37296128 PMC: 10256735. DOI: 10.1038/s41598-023-34172-1.

Support-Activity Relationship in Heterogeneous Catalysis for Biomass Valorization and Fine-Chemicals Production.

Lazzarini A, Colaiezzi R, Gabriele F, Crucianelli M Materials (Basel). 2021; 14(22).

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