Residues Analysis and Dissipation Dynamics of Broflanilide in Rice and Its Related Environmental Samples

Overview

Journal Int J Anal Chem

Publisher Wiley

Specialty Chemistry

Date 2020 Dec 31

PMID 33381186

Citations 3

Authors

Guai Xie

Wenwen Zhou

Mingxia Jin

Ailin Yu

Lei Rao

Horan Jia

Juan Luo

Yichang He

Baotong Li

Affiliations

Soon will be listed here.

Abstract

Herein, we present a method for the quantitative analysis of broflanilide residues in water, soil, and rice samples from a paddy field in Jiangxi Province, China. The quick, easy, cheap, effective, rugged, and safe (QuEChERS) method was optimized for the extraction and purification of broflanilide residues. Residual broflanilide concentrations in different matrices were then determined by high-performance liquid chromatography (HPLC). The calibration curve of broflanilide showed good linearity in all matrices for concentrations between 0.005 and 1 mg·L, with a correlation coefficient greater than 0.99. The matrix effect varied from -69% to -54%, indicating matrix suppression. The average recoveries ranged between 85.82% and 97.46%, with relative standard deviations of 3.29%-8.15%. The limits of detection ranged from 0.16 to 1.67 g·kg, and the limits of quantification were in the range of 0.54 to 5.48 g·kg. Dissipation dynamic tests indicated broflanilide half-lives of 0.46-2.46, 2.09-5.34, and 1.31-3.32 days in soil, water, and rice straw, respectively. Broflanilide was dissipated more rapidly in water than in soil and rice straw. More than 90% of broflanilide residues dissipated within 14 days. The final residues of broflanilide in rice were all below LOQ at harvest.

Citing Articles

Optimization of Ferimzone and Tricyclazole Analysis in Rice Straw Using QuEChERS Method and Its Application in UAV-Sprayed Residue Study.

Kim S, Baek J, Eun H, Lee Y, Kim S, Jeong M Foods. 2024; 13(21).

PMID: 39517301 PMC: 11545821. DOI: 10.3390/foods13213517.

Optimization and Application of the QuEChERS-UHPLC-QTOF-MS Method for the Determination of Broflanilide Residues in Agricultural Soils.

Nie X, Xie G, Huo Z, Zhang B, Lu H, Huang Y Molecules. 2024; 29(7).

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Establishment of Toxicity and Susceptibility Baseline of Broflanilide for Glove.

Li R, Cheng S, Chen Z, Guo T, Liang P, Zhen C Insects. 2022; 13(11).

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References

Banerjee K, Oulkar D, Dasgupta S, Patil S, Patil S, Savant R . Validation and uncertainty analysis of a multi-residue method for pesticides in grapes using ethyl acetate extraction and liquid chromatography-tandem mass spectrometry. J Chromatogr A. 2007; 1173(1-2):98-109. DOI: 10.1016/j.chroma.2007.10.013. View

Nakao T, Banba S, Nomura M, Hirase K . Meta-diamide insecticides acting on distinct sites of RDL GABA receptor from those for conventional noncompetitive antagonists. Insect Biochem Mol Biol. 2013; 43(4):366-75. DOI: 10.1016/j.ibmb.2013.02.002. View

Seccia S, Albrizio S, Fidente P, Montesano D . Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples. J Chromatogr A. 2011; 1218(9):1253-9. DOI: 10.1016/j.chroma.2011.01.006. View

Lafleur A, Plummer E . Effect of column and mobile phase modifications on retention behavior in size exclusion chromatography of polycyclic aromatic hydrocarbons on poly(divinylbenzene). J Chromatogr Sci. 1991; 29(12):532-7. DOI: 10.1093/chromsci/29.12.532. View

Tsochatzis E, Menkissoglu-Spiroudi U, Karpouzas D, Tzimou-Tsitouridou R . A multi-residue method for pesticide residue analysis in rice grains using matrix solid-phase dispersion extraction and high-performance liquid chromatography-diode array detection. Anal Bioanal Chem. 2010; 397(6):2181-90. DOI: 10.1007/s00216-010-3645-4. View

Fanigliulo A, De Filippis P, Curcuruto O, Repeto P, Roveda D, Hartenstein M . Development and validation of a stability indicating method for S-carboxymethyl-L-cysteine and related degradation products in oral syrup formulation. J Pharm Biomed Anal. 2015; 115:39-47. DOI: 10.1016/j.jpba.2015.06.031. View

Xue Q, Qi Y, Liu F . Ultra-high performance liquid chromatography-electrospray tandem mass spectrometry for the analysis of antibiotic residues in environmental waters. Environ Sci Pollut Res Int. 2015; 22(21):16857-67. DOI: 10.1007/s11356-015-4900-1. View

Garrido Frenich A, Gonzalez-Rodriguez M, Arrebola F, Martinez Vidal J . Potentiality of gas chromatography-triple quadrupole mass spectrometry in vanguard and rearguard methods of pesticide residues in vegetables. Anal Chem. 2005; 77(14):4640-8. DOI: 10.1021/ac050252o. View

Lehotay S, Son K, Kwon H, Koesukwiwat U, Fu W, Mastovska K . Comparison of QuEChERS sample preparation methods for the analysis of pesticide residues in fruits and vegetables. J Chromatogr A. 2010; 1217(16):2548-60. DOI: 10.1016/j.chroma.2010.01.044. View

10.

Wu J, Wang K, Zhang Y, Zhang H . Determination and study on dissipation and residue determination of cyhalofop-butyl and its metabolite using HPLC-MS/MS in a rice ecosystem. Environ Monit Assess. 2014; 186(10):6959-67. DOI: 10.1007/s10661-014-3902-7. View

11.

Zhang Q, Zhao Y, Fan S, Bai A, Li X, Pan C . Dissipation and residues of bispyribac-sodium in rice and environment. Environ Monit Assess. 2013; 185(12):9743-9. DOI: 10.1007/s10661-013-3287-z. View

12.

Kuang Y, Qiu F, Kong W, Luo J, Cheng H, Yang M . Simultaneous quantification of mycotoxins and pesticide residues in ginseng with one-step extraction using ultra-high performance liquid chromatography-electrospray ionization tandem mass spectrometry. J Chromatogr B Analyt Technol Biomed Life Sci. 2013; 939:98-107. DOI: 10.1016/j.jchromb.2013.09.013. View

13.

Brondi S, de Macedo A, de Souza G, Nogueira A . Application of QuEChERS method and gas chromatography-mass spectrometry for the analysis of cypermethrin residue in milk. J Environ Sci Health B. 2011; 46(8):671-7. DOI: 10.1080/03601234.2012.592058. View

14.

Tsao R, Yang R, Young J, Zhu H . Polyphenolic profiles in eight apple cultivars using high-performance liquid chromatography (HPLC). J Agric Food Chem. 2003; 51(21):6347-53. DOI: 10.1021/jf0346298. View

15.

Paya P, Anastassiades M, Mack D, Sigalova I, Tasdelen B, Oliva J . Analysis of pesticide residues using the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) pesticide multiresidue method in combination with gas and liquid chromatography and tandem mass spectrometric detection. Anal Bioanal Chem. 2007; 389(6):1697-714. DOI: 10.1007/s00216-007-1610-7. View

16.

Li C, Yang T, Huangfu W, Wu Y . Residues and dynamics of pymetrozine in rice field ecosystem. Chemosphere. 2010; 82(6):901-4. DOI: 10.1016/j.chemosphere.2010.10.053. View

17.

Luo X, Qin X, Liu Z, Chen D, Yu W, Zhang K . Determination, residue and risk assessment of trifloxystrobin, trifloxystrobin acid and tebuconazole in Chinese rice consumption. Biomed Chromatogr. 2019; 34(1):e4694. DOI: 10.1002/bmc.4694. View

18.

Sanchez M, Estrada I, Martinez O, Martin-Villacorta J, Aller A, Moran A . Influence of the application of sewage sludge on the degradation of pesticides in the soil. Chemosphere. 2004; 57(7):673-9. DOI: 10.1016/j.chemosphere.2004.07.023. View

19.

de Melo Plese L, Paraiba L, Foloni L, Pimentel Trevizan L . Kinetics of carbosulfan hydrolysis to carbofuran and the subsequent degradation of this last compound in irrigated rice fields. Chemosphere. 2005; 60(2):149-56. DOI: 10.1016/j.chemosphere.2005.02.049. View

20.

Zhao P, Wang L, Chen L, Pan C . Residue dynamics of clopyralid and picloram in rape plant rapeseed and field soil. Bull Environ Contam Toxicol. 2010; 86(1):78-82. DOI: 10.1007/s00128-010-0184-9. View