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Facile Synthesis of G-CN/TiO/Hectorite Z-Scheme Composite and Its Visible Photocatalytic Degradation of Rhodamine B

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Publisher MDPI
Date 2020 Nov 26
PMID 33238637
Citations 1
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Abstract

A novel g-CN/TiO/hectorite Z-scheme composites with oxygen vacancy (Vo) defects and Ti were synthesized by so-gel method and high temperature solid phase reaction. This composite exhibited high visible photo-catalytic degradation of rhodamine B (RhB). The apparent rate constant of g-CN/TiO/hectorite was 0.01705 min, which is approximately 5.38 and 4.88 times that of P25 and g-CN, respectively. The enhancement of photo-catalytic efficiency of the composites can be attributed to the great light harvesting ability, high specific surface area and effective separation of electrons(e) and holes(h). The F element from Hectorite causes the formation of Vo and Ti in TiO, making it responsive to visible light. The effective separation of e and h mainly results from Z-scheme transfer of photo-produced electrons in g-CN/TiO interface. The composites can be easily recycled and the degradation rate of the RhB still reached 84% after five cycles, indicating its good reusability.

Citing Articles

One-Pot Synthesis of Cellulose-Based Carbon Aerogel Loaded with TiO and g-CN and Its Photocatalytic Degradation of Rhodamine B.

Liu F, Fan M, Liu X, Chen J Nanomaterials (Basel). 2024; 14(13).

PMID: 38998746 PMC: 11243333. DOI: 10.3390/nano14131141.

References
1.
Zhu Y, Fan W, Zhou T, Li X . Removal of chelated heavy metals from aqueous solution: A review of current methods and mechanisms. Sci Total Environ. 2019; 678:253-266. DOI: 10.1016/j.scitotenv.2019.04.416. View

2.
Fujishima A, Honda K . Electrochemical photolysis of water at a semiconductor electrode. Nature. 1972; 238(5358):37-8. DOI: 10.1038/238037a0. View

3.
Liu X, Sun J, Duan S, Wang Y, Hayat T, Alsaedi A . A Valuable Biochar from Poplar Catkins with High Adsorption Capacity for Both Organic Pollutants and Inorganic Heavy Metal Ions. Sci Rep. 2017; 7(1):10033. PMC: 5577165. DOI: 10.1038/s41598-017-09446-0. View

4.
Liu J, Zhang G . Recent advances in synthesis and applications of clay-based photocatalysts: a review. Phys Chem Chem Phys. 2014; 16(18):8178-92. DOI: 10.1039/c3cp54146k. View

5.
Zhang Y, Pan Q, Chai G, Liang M, Dong G, Zhang Q . Synthesis and luminescence mechanism of multicolor-emitting g-C3N4 nanopowders by low temperature thermal condensation of melamine. Sci Rep. 2013; 3:1943. PMC: 3673641. DOI: 10.1038/srep01943. View